New method of chemical synthesis of O-linked glycopeptides
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The diphenylketone Shiff - base appeared to be a very good protection for amino groups of serine and threonine for glycosylation reaction. O-glycosides of these aminoacids with different monosaccharides, aminosugars and deoxysugars were obtained with excelent yield and very high stereoselectivity. Products of glycosylation reactions were used as building blocks for solid phase glycopeptide synthesis.
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J.Ramza, ul. Rydygiera 8, 01-793 Warszawa, Poland