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2013 | 123 | 2 | 207-208
Article title

Behavior of Co^{2+} Cations in the Aqueous and Alcoholic Solution of CoCl_2·6H_2O

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EN
Abstracts
EN
We investigated the optical properties of Co^{2+} cations in the aqueous and alcoholic solution of CoCl_2·6H_2O at room temperature. We measured the absorption spectra of these solutions in the spectral region 395-800 nm. The Racah parameters and the exchange integrals of the aqueous complex [Co(H_2O)_6]^{2+} are calculated. The parameters D_{t} and D_{s} are also calculated on the basis of our experimental data. The parameters δ σ and δπ which are connected with the symmetry of this complex are also determined.
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Year
Volume
123
Issue
2
Pages
207-208
Physical description
Dates
published
2013-02
References
  • [1] R. Drago, Physical Methods in Chemistry, Vol. 2, 'Peace', Moscow 1981
  • [2] O.G. Holmes, D.S. Mc Clure, J. Chem. Phys. 26, 1686 (1957)
  • [3] C.K. Jorgensen, Acta Chem. Scand. 8, 1495 (1954)
  • [4] S. Koide, Philos. Mag. 4, 243 (1959)
  • [5] D.S. Mc Clure, Advances in the Chemistry of Coordination Compounds, Macmillan, New York 1961, p. 498
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Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv123n2015kz
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