Behavior of Co^{2+} Cations in the Aqueous and Alcoholic Solution of CoCl_2·6H_2O

• Authors: P. Petkova , V. Nedkov
• Languages of publication: EN

Abstracts

EN

We investigated the optical properties of Co^{2+} cations in the aqueous and alcoholic solution of CoCl_2·6H_2O at room temperature. We measured the absorption spectra of these solutions in the spectral region 395-800 nm. The Racah parameters and the exchange integrals of the aqueous complex [Co(H_2O)_6]^{2+} are calculated. The parameters D_{t} and D_{s} are also calculated on the basis of our experimental data. The parameters δ σ and δπ which are connected with the symmetry of this complex are also determined.

Keywords

EN

78.15.+e; 78.40.Dw

Discipline

• 78.40.Dw: Liquids
• 78.15.+e: Optical properties of fluid materials, supercritical fluids and liquid crystals(for reactions in supercritical fluids, see 82.33.De)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2013
• Volume: 123
• Issue: 2
• Pages: 207-208

Dates

published

2013-02

Contributors

author

P. Petkova

• Shumen University "Konstantin Preslavsky", 115 Universitetska Str., 9712 Shumen, Bulgaria

author

V. Nedkov

• Shumen University "Konstantin Preslavsky", 115 Universitetska Str., 9712 Shumen, Bulgaria

References

• [1] R. Drago, Physical Methods in Chemistry, Vol. 2, 'Peace', Moscow 1981
• [2] O.G. Holmes, D.S. Mc Clure, J. Chem. Phys. 26, 1686 (1957)
• [3] C.K. Jorgensen, Acta Chem. Scand. 8, 1495 (1954)
• [4] S. Koide, Philos. Mag. 4, 243 (1959)
• [5] D.S. Mc Clure, Advances in the Chemistry of Coordination Compounds, Macmillan, New York 1961, p. 498

Identifiers

DOI

10.12693/APhysPolA.123.207