Title variants
Languages of publication
Abstracts
We have reported herein the synthesis of a novel quinone derivative ligand containing the Schiff base and its Cu(II) complex starting from 1,4-naphthoquinone. Synthesized compounds were characterized using the Fourier transform infrared, UV-Vis, elemental analysis, inductively coupled plasma optical emission spectrometry, molar conductivity, and magnetic susceptibility measurements. The free ligand was also characterized by ¹H- and ¹³C-NMR spectra. Elemental analyses, stoichiometric and spectroscopic data indicated that the metal:ligand ratio is 1:2 and octahedral structure is proposed for the metal complex of the Schiff base ligand. Computational quantum calculations were also performed using DFT/B3LYP level of theory with 6-311++G(d,p) basis set for the synthesized ligand. It was found that the experimental and theoretical spectroscopic data were consistent.
Keywords
Journal
Year
Volume
Issue
Pages
239-243
Physical description
Dates
published
2018-02
Contributors
author
- Faculty of Education, Mehmet Akif Ersoy University, Burdur, Turkey
author
- Faculty of Science and Arts, Süleyman Demirel University, Isparta, Turkey
References
- [1] S. Spyroudis, Molecules 5, 1291 (2000), doi: 10.3390/51201291
- [2] M. Tisler, Heterocyclic Quinones, in: Advances in Heterocyclic Chemistry, Ed. A.R. Katritzky, Academic Press, London 1989, p. 37
- [3] D.N. Dhar, C.L. Taploo, J. Sci. Ind. Res. 41, 501 (1982)
- [4] P. Przybylski, A. Huczynski, K. Pyta, B. Brzezinski, F. Bartl, Curr. Org. Chem. 13, 124 (2009), doi: 10.2174/138527209787193774
- [5] E.M. Nour, A.A. Taha, I.S. Alnaimi, Inorg. Chim. Acta 141, 139 (1988), doi: 10.1016/S0020-1693(00)86387-2
- [6] E.M. Nour, A.M. Al-Kority, S.A. Sadeek, S.M. Teleb, Syn. React. Inorg. Met. 23, 39 (1993), doi: 10.1080/15533179308016615
- [7] W. Wang, F.L. Zeng, X. Wang, M.Y. Tan, Polyhedron 15, 1699 (1996), doi: 10.1016/0277-5387(95)00403-3
- [8] M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Suzerain, M.A. Robb, J.R. Cheeseman Jr., J.A. Montgomery, T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J.E. Knox, H.P. Hratchian, J.B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, Gaussian 09 (now Gaussian 16), Gaussian Inc., Wallingford (CT) 2016 http://gaussian.com/gaussian16/
- [9] GaussView, Revision 5.0.9, R. Dennington, T.A. Keith, J.M. Millam, Semichem Inc., Shawnee Mission, KS, 2009
- [10] R. Ditchfield, J. Chem. Phys. 56, 5688 (1972), doi: 10.1063/1.1677088
- [11] K. Wolinski, J.F. Hinton, P. Pulay, J. Am. Chem. Soc. 112, 8251 (1990), doi: 10.1021/ja00179a005
- [12] A. Coşkun, F. Yılmaz, Turk. J. Chem. 32, 305 (2008)
- [13] P.E. Aranha, M.P. dos Santos, S. Romera, E.R. Dockal, Polyhedron 26, 1373 (2007), doi: 10.1016/j.poly.2006.11.005
- [14] A. Abbas, H. Gokce, S. Bahceli, M.M. Naseer, J. Mol. Struct. 1075, 352 (2014), doi: 10.1016/j.molstruc.2014.07.00
- [15] K. Balcı, S. Akyuz, Vibrat. Spectrosc. 48, 215 (2008), doi: 10.1016/j.vibspec.2008.02.001
- [16] N. Sundaraganesan, S. Ilakiamani, H. Saleem, P.M. Wojciechowski, D. Michalska, Spectrochim. Acta A 61, 2995 (2005), doi: 10.1016/j.saa.2004.11.016
- [17] F. Karipcin, H.İ. Uçan, İ. Karataş, Transit. Met. Chem. 27, 813 (2002), doi: 10.1023/A:1021315931250
- [18] W.J. Geary, Coord. Chem. Rev. 7, 81 (1971), doi: 10.1016/S0010-8545(00)80009-0
- [19] A.D. Becke, Phys. Rev. A 38, 3098 (1988), doi: 10.1103/PhysRevA.38.3098
- [20] C. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37, 785 (1988), doi: 10.1103/PhysRevB.37.785
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-app133z2p07kz