Synthesis, Characterization and DFT Calculations of 4-((2-Hydroxyethyl)imino)naphthalen-1(4H)-One and its Cu(II) Complex

• Authors: G. Gorgulu , B. Dede
• Languages of publication: EN

Abstracts

EN

We have reported herein the synthesis of a novel quinone derivative ligand containing the Schiff base and its Cu(II) complex starting from 1,4-naphthoquinone. Synthesized compounds were characterized using the Fourier transform infrared, UV-Vis, elemental analysis, inductively coupled plasma optical emission spectrometry, molar conductivity, and magnetic susceptibility measurements. The free ligand was also characterized by ¹H- and ¹³C-NMR spectra. Elemental analyses, stoichiometric and spectroscopic data indicated that the metal:ligand ratio is 1:2 and octahedral structure is proposed for the metal complex of the Schiff base ligand. Computational quantum calculations were also performed using DFT/B3LYP level of theory with 6-311++G(d,p) basis set for the synthesized ligand. It was found that the experimental and theoretical spectroscopic data were consistent.

Keywords

EN

Schiff base; quinone; metal complex; spectroscopy; copper(II); DFT

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 2
• Pages: 239-243

Dates

published

2018-02

Contributors

author

G. Gorgulu

• Faculty of Education, Mehmet Akif Ersoy University, Burdur, Turkey

author

B. Dede

• Faculty of Science and Arts, Süleyman Demirel University, Isparta, Turkey

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Identifiers

DOI

10.12693/APhysPolA.131.239