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Number of results
2010 | 65 | 1-8

Article title

Synergistic effects in hydrodechlorination of organic compounds catalyzed by metals

Content

Title variants

Languages of publication

EN

Abstracts

EN
The search for the most suitable hydrodechlorination catalysts should consider both the C-Cl bond strength in a molecule subjected to reaction and the metal-chlorine bond, which should be neither too strong nor too weak. An improvement of Pd- and Pt-based catalysts can be achieved by alloying with metals which bind chlorine even less strongly, e.g. with gold. Addition of platinum to palladium would also be beneficial because of metal-chloride bond energy considerations. Analogous effects occur in the hydrodechlorination of dichlorodifluoromethane and 1,2-dichloroethane, the molecules characterized by stronger carbon-chlorine bonds.

Keywords

Year

Volume

65

Pages

1-8

Physical description

Dates

published
1 - 1 - 2010
online
28 - 1 - 2011

Contributors

author
  • Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland
  • Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland
author

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10063-010-0001-7
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