Synergistic effects in hydrodechlorination of organic compounds catalyzed by metals

• Authors: M. Bonarowska , A. Śrębowata , Z. Karpiński
• Languages of publication: EN

Abstracts

EN

The search for the most suitable hydrodechlorination catalysts should consider both the C-Cl bond strength in a molecule subjected to reaction and the metal-chlorine bond, which should be neither too strong nor too weak. An improvement of Pd- and Pt-based catalysts can be achieved by alloying with metals which bind chlorine even less strongly, e.g. with gold. Addition of platinum to palladium would also be beneficial because of metal-chloride bond energy considerations. Analogous effects occur in the hydrodechlorination of dichlorodifluoromethane and 1,2-dichloroethane, the molecules characterized by stronger carbon-chlorine bonds.

• Publisher: Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
• Journal: Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
• Year: 2010
• Volume: 65
• Pages: 1-8

Dates

published

1 - 1 - 2010

online

28 - 1 - 2011

Contributors

author

M. Bonarowska

• Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland

author

A. Śrębowata

• Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland

author

Z. Karpiński

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Identifiers

DOI

10.2478/v10063-010-0001-7