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2010 | 65 | 1-8
Article title

Synergistic effects in hydrodechlorination of organic compounds catalyzed by metals

Content
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Languages of publication
EN
Abstracts
EN
The search for the most suitable hydrodechlorination catalysts should consider both the C-Cl bond strength in a molecule subjected to reaction and the metal-chlorine bond, which should be neither too strong nor too weak. An improvement of Pd- and Pt-based catalysts can be achieved by alloying with metals which bind chlorine even less strongly, e.g. with gold. Addition of platinum to palladium would also be beneficial because of metal-chloride bond energy considerations. Analogous effects occur in the hydrodechlorination of dichlorodifluoromethane and 1,2-dichloroethane, the molecules characterized by stronger carbon-chlorine bonds.
Keywords
Year
Volume
65
Pages
1-8
Physical description
Dates
published
1 - 1 - 2010
online
28 - 1 - 2011
Contributors
author
  • Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland
  • Institute of Physical Chemistry of PAS, ul. Kasprzaka 44/52, 01-224 Warszawa, Poland
author
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10063-010-0001-7
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