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2012 | 14 | 4 | 35-41
Article title

Meso-tetraphenylporphyriniron(iii) chloride catalyzed oxidation of aniline and its substituents by magnesium monoperoxyphthalate in aqueous acetic acid medium

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EN
Abstracts
EN
The catalytic properties of the first generation catalyst meso-tetraphenylporphyriniron(III) chloride and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in the oxidation of aniline and its substituents in acetic acid medium. The thermodynamic parameters for the oxidation have been determined and discussed. It confirms the Exner relationship (only at the low range of temperatures) and also some of the activation parameters to the isokinetic relationships. The magnesium monoperoxyphthalate oxidation with 18 ortho- meta- and para-substituted anilines fulfills with isokinetic relationship but not to any of the linear free energy relationships. The reaction mechanism and the rate law were proposed.
Publisher

Year
Volume
14
Issue
4
Pages
35-41
Physical description
Dates
published
1 - 12 - 2012
online
12 - 01 - 2013
Contributors
author
  • Sona College of Technology, Department of Chemistry, Salem – 636005, Tamilnadu, India
  • Sona College of Technology, Department of Chemistry, Salem – 636005, Tamilnadu, India, drkk@sonatech.ac.in
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10026-012-0099-9
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