Meso-tetraphenylporphyriniron(iii) chloride catalyzed oxidation of aniline and its substituents by magnesium monoperoxyphthalate in aqueous acetic acid medium

• Authors: Raja Manickam , Karunakaran Kulandaivelu
• Languages of publication: EN

Abstracts

EN

The catalytic properties of the first generation catalyst meso-tetraphenylporphyriniron(III) chloride and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in the oxidation of aniline and its substituents in acetic acid medium. The thermodynamic parameters for the oxidation have been determined and discussed. It confirms the Exner relationship (only at the low range of temperatures) and also some of the activation parameters to the isokinetic relationships. The magnesium monoperoxyphthalate oxidation with 18 ortho- meta- and para-substituted anilines fulfills with isokinetic relationship but not to any of the linear free energy relationships. The reaction mechanism and the rate law were proposed.

Keywords

EN

Aniline oxidation; kinetics; mechanism; magnesium monoperoxyphthalate; mesotetraphenylporphyriniron( III) chloride; catalyst.

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2012
• Volume: 14
• Issue: 4
• Pages: 35-41

Dates

published

1 - 12 - 2012

online

12 - 01 - 2013

Contributors

author

Raja Manickam

• Sona College of Technology, Department of Chemistry, Salem – 636005, Tamilnadu, India

author

Karunakaran Kulandaivelu

• Sona College of Technology, Department of Chemistry, Salem – 636005, Tamilnadu, India

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Identifiers

DOI

10.2478/v10026-012-0099-9