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Number of results
2007 | 9 | 4 | 68-71
Article title

Application of the design of experiments in the epoxidation process of 1,5,9-cyclododecatriene

Content
Title variants
Languages of publication
EN
Abstracts
EN
An influence of the molar ratio of cis, trans, trans-1,5,9-cyclododecatriene to tert-butyl hydroperoxide, the concentration of the catalyst and the reaction time on the performance of the epoxidation process of cis, trans, trans-1,5,9-cyclodecatriene with tert-butyl hydroperoxide at the presence of molybdenum hexacarbonyl Mo(CO)6 was examined. Examinations were performed using statistical methods of the design of experiments. A mathematical model describing the influence of the parameters on conversion cis, trans, trans-1,5,9-cyclododecatriene was obtained. An analysis of the data and rests was performed and an optimal value of conversion of cis, trans, trans-1,5,9-cyclododecatriene was established.
Publisher

Year
Volume
9
Issue
4
Pages
68-71
Physical description
Dates
published
1 - 12 - 2007
online
30 - 1 - 2008
Contributors
  • Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland
author
  • Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland
References
  • Fisher R. A. Design of experiments, Oliver & Boyd, London, 1935.
  • Mańczak K. Technika planowania eksperymentu, WNT, Warszawa, 1976.
  • ---
  • Polański Z. Planowanie doświadczeń w technice, PWN, Warszawa, 1984.
  • Sharpless K. B., Verhoeven T. R. Metal catalysed, highly selective oxygenation of olefins and acetylenes with tert-butyl hydroperoxide. Practical consideration and mechanisms, Aldrichim. Acta, 1979, 12, 63 - 74.
  • Montgomery D. C. Design and analysis of experiments, John Wiley & Sons Inc., 2005.
  • Czermiński J. B., Iwasiewicz A., Paszek Z., Sikorski A. Metody statystyczne dla chemików, PWN, Warszawa, 1992.
  • Draper N. R., Smith H. Applied regression analysis, John Wiley & Sons Inc, 1998.
  • Jobson J. D. Applied multivariate data analysis, Springer-Verlag, New York, 1991.
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10026-007-0093-9
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