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Journal
2008 | 6 | 3 | 454-461
Article title

Kinetics of the formation and structure of oligoperoxide nanolayers and grafted polymer brushes on glass plate surface

Content
Title variants
Languages of publication
EN
Abstracts
EN
Functional oligoperoxide surfactants and coordinating oligoperoxide metal complexes were studied as modifiers of glass flat plates to provide the localization of radical forming sites and other functional fragments in adsorbed polymeric layers of a nanoscale thickness. Both the kinetics of the coating formation and properties of the nanolayers witness the dependence of the packing density of oligoperoxide molecules in the coatings on the oligoperoxide natures, concentrations and conditions of the sorption modification. The availability of definite amount of peroxide groups in formed nanolayer provides the possibility of controlled radical graft polymerization initiated from modified surface leading to reliable surface protection, functionality and targeted surface hydrophilic-hydrophobic properties.
Publisher
Journal
Year
Volume
6
Issue
3
Pages
454-461
Physical description
Dates
published
1 - 9 - 2008
online
17 - 7 - 2008
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11534-008-0097-y
Identifiers
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