Kinetics of the formation and structure of oligoperoxide nanolayers and grafted polymer brushes on glass plate surface

• Authors: Andriy Kostruba , Alexander Zaichenko , Natalya Mitina , Kateryna Rayevska , Kateryna Hertsyk
• Languages of publication: EN

Abstracts

EN

Functional oligoperoxide surfactants and coordinating oligoperoxide metal complexes were studied as modifiers of glass flat plates to provide the localization of radical forming sites and other functional fragments in adsorbed polymeric layers of a nanoscale thickness. Both the kinetics of the coating formation and properties of the nanolayers witness the dependence of the packing density of oligoperoxide molecules in the coatings on the oligoperoxide natures, concentrations and conditions of the sorption modification. The availability of definite amount of peroxide groups in formed nanolayer provides the possibility of controlled radical graft polymerization initiated from modified surface leading to reliable surface protection, functionality and targeted surface hydrophilic-hydrophobic properties.

Keywords

EN

ellipsometry; oligoperoxide surfactants; adsorption; nanolayer; grafting

Discipline

• 78.66.Qn: Polymers; organic compounds
• 07.60.Fs: Polarimeters and ellipsometers

• Publisher: De Gruyter Open
• Journal: Open Physics
• Year: 2008
• Volume: 6
• Issue: 3
• Pages: 454-461

Dates

published

1 - 9 - 2008

online

17 - 7 - 2008

Contributors

author

Andriy Kostruba

author

Alexander Zaichenko

• Lviv Polytechnic National University, S. Bandera Str., 12, Lviv, 79013, Ukraine

author

Natalya Mitina

• Lviv Polytechnic National University, S. Bandera Str., 12, Lviv, 79013, Ukraine

author

Kateryna Rayevska

• Lviv Polytechnic National University, S. Bandera Str., 12, Lviv, 79013, Ukraine

author

Kateryna Hertsyk

• Lviv Ivan Franko National University, Cyril and Mephodiy Str., 6, Lviv, 79011, Ukraine

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Identifiers

DOI

10.2478/s11534-008-0097-y