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Journal
2014 | 12 | 3 | 325-331
Article title

Determination of vitamin B6 (pyridoxine hydrochloride) based on a novel BZ oscillating reaction system catalyzed by a macrocyclic complex

Content
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Languages of publication
EN
Abstracts
EN
This paper reports a new method for determination of VB6 (pyridoxine hydrochloride) by its perturbation effects on a novel Belousov-Zhabotinskii (BZ) oscillating system. This novel BZ system, in which malic acid serves as the substrate, contains an enzyme-like complex, macrocyclic complex {[CuL](ClO4)2}, as catalyst. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. Results show that the addition of pyridoxine hydrochloride can perturb the oscillation amplitude and period, and the change of the oscillation amplitude is linearly proportional to the concentration of pyridoxine hydrochloride in the range of 5×10−7−2.5×10−4 M. The obtained RSD with seven samples is 3.073%. An assay of pharmaceutical tablets of vitamin B6 was evaluated. Some foreign ions were studied with respect to their possible influence on the determination of pyridoxine hydrochloride. The factors which influence this reaction include the concentration of reactant, the temperature of the reaction, property of catalyst, etc. Furthermore, the possible reaction mechanism has been proposed using the Field-Körös-Noyes (FKN) model.
Publisher

Journal
Year
Volume
12
Issue
3
Pages
325-331
Physical description
Dates
published
1 - 3 - 2014
online
21 - 12 - 2013
Contributors
author
  • Anhui University
author
  • Anhui University
author
  • Anhui University
author
author
  • East China Jiaotong University
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0383-4
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