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Journal
2014 | 12 | 2 | 220-226
Article title

The synthesis, structure and physical properties of lanthanide(III) complexes with nicotinic acid

Content
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EN
Abstracts
EN
This article reports the synthesis of novel, rare-earth coordination complexes with nicotinic acid. Three compounds with the general formula Ln2[(C5H4NCOO)6(H2O)4] (Ln = Yb, 1; Ln = Gd, 2; Ln = Nd, 3) were prepared from relatively cheap and readily available reactants. Their compositions and structure were characterized by IR spectroscopy and single-crystal X-ray diffraction. The magnetic and thermogravimetric properties were also studied. The complexes consist of centrosymetric, dimeric molecules having all six nicotinato ligands coordinated with the central atom in the bidentate mode. The coordination environment of the Ln3+ for all three compounds is 8. Here we describe the crystal structure of Yb and Gd complexes with nicotinic acid.
Publisher
Journal
Year
Volume
12
Issue
2
Pages
220-226
Physical description
Dates
published
1 - 2 - 2014
online
27 - 11 - 2013
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0366-5
Identifiers
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