The synthesis, structure and physical properties of lanthanide(III) complexes with nicotinic acid

• Authors: Nuša Hojnik , Matjaž Kristl , Amalija Golobič , Zvonko Jagličić , Miha Drofenik
• Languages of publication: EN

Abstracts

EN

This article reports the synthesis of novel, rare-earth coordination complexes with nicotinic acid. Three compounds with the general formula Ln2[(C5H4NCOO)6(H2O)4] (Ln = Yb, 1; Ln = Gd, 2; Ln = Nd, 3) were prepared from relatively cheap and readily available reactants. Their compositions and structure were characterized by IR spectroscopy and single-crystal X-ray diffraction. The magnetic and thermogravimetric properties were also studied. The complexes consist of centrosymetric, dimeric molecules having all six nicotinato ligands coordinated with the central atom in the bidentate mode. The coordination environment of the Ln3+ for all three compounds is 8. Here we describe the crystal structure of Yb and Gd complexes with nicotinic acid.

Keywords

EN

Lanthanides; Nicotinic acid; Magnetic properties; X-ray structure determination; Hydrogen bonds

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 2
• Pages: 220-226

Dates

published

1 - 2 - 2014

online

27 - 11 - 2013

Contributors

author

Nuša Hojnik

• University of Maribor

author

Matjaž Kristl

• University of Maribor

author

Amalija Golobič

• University of Ljubljana

author

Zvonko Jagličić

author

Miha Drofenik

References

• [1] J. Kido, Y. Okamoto, Chem. Rev. 102, 2357 (2002) http://dx.doi.org/10.1021/cr010448y[Crossref]
• [2] A. Gomez-Hens, M.P. Aguilar-Caballos, Trends. Anal. Chem. 21, 13 (2002) http://dx.doi.org/10.1016/S0165-9936(01)00139-X[Crossref]
• [3] R.D. Rajasekhar, R. Laura, E. Pedro, M. Lawrence, Bioconjugate Chem. 22, 1402 (2011) http://dx.doi.org/10.1021/bc200131k[Crossref]
• [4] J. Hongfei, W. Guilan, Z. Wenzhu, L. Xiaoyu, Y. Zhiqiang, J. Dayong, Y. Jingli, L. Zhiguang, J. Fluoresc. 20, 321 (2010) http://dx.doi.org/10.1007/s10895-009-0559-7[Crossref]
• [5] S. Faulkner, S.J.A. Pope, B.P. Burton-Pye, Appl. Spectrosc. Rev. 40, 1 (2005) http://dx.doi.org/10.1081/ASR-200038308[Crossref]
• [6] J.W. Moore, M.D. Glick, W.A. Baker Jr., Am. Chem. J. 94, 6 (1971)
• [7] G. Jia, G.L. Law, K.L. Wong, P.A. Tanner, W.T. Wong, Inorg. Chem. 47, 9431 (2008) http://dx.doi.org/10.1021/ic8010103[Crossref]
• [8] L. Shuangxi, J. Linpei, Nat. Sci. 32, 96 (1996)
• [9] B. Yan, Y. Bai, Z. Chen, J. Mol. Struct. 741, 141 (2005) http://dx.doi.org/10.1016/j.molstruc.2005.02.004[Crossref]
• [10] W.T. Chen, Acta. Chim. Slov. 58, 144 (2011) [PubMed]
• [11] Q. Yang, J.P. Zhao, B.W. Hu, X.F. Zhang, X.H. Bu, Inorg. Chem. 49, 3746 (2010) http://dx.doi.org/10.1021/ic9021257[Crossref]
• [12] M.E. Chapman, P. Ayyappan, B.M. Foxman, G.T. Yee, W. Lin, Cryst. Growth. Des. 1, 159 (2001) http://dx.doi.org/10.1021/cg005519l[Crossref]
• [13] Q.H. Jin, X. Li, Y.Q. Zou, K.B. Yu, Z. Kristallogr. 218, 45 (2003)
• [14] K. Binnemans, Rare earths β-diketonates in Handbook on the Physics and Chemistry of Rare Earths (Elsevier, Amsterdam, 2005)
• [15] N. Filipescu, W.F. Sager, F.A. Serafin, J. Phys. Chem. 68, 3324 (1964) http://dx.doi.org/10.1021/j100793a039[Crossref]
• [16] W. Chen, S. Fukuzumi, Inorg. Chem. 48, 3800 (2009) http://dx.doi.org/10.1021/ic9000279[Crossref]
• [17] L. Shen, M. Shi, F. Li, D. Zhang, X. Li, E. Shi, T. Yi, Y. Du, C. Huang, Inorg. Chem. 45, 6188 (2006) http://dx.doi.org/10.1021/ic052148v[Crossref]
• [18] CrysAlis PRO. Version 1.171.35.11 (Agilent Technologies, Yarnton, Oxfordshire, England, 2011)
• [19] A. Altomare, M.C. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Cryst. 32, 115 (1999) http://dx.doi.org/10.1107/S0021889898007717[Crossref]
• [20] G.M. Sheldrick, Acta. Cryst. A. 64, 112 (2008) http://dx.doi.org/10.1107/S0108767307043930[Crossref]
• [21] L.J. Farrugia, J. Appl. Cryst. 30, 565 (1997) http://dx.doi.org/10.1107/S0021889897003117[Crossref]
• [22] C.F. Macrae, P.R. Edgington, P. McCabe, E. Pidcock, G.P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Cryst. 39, 453 (2006) http://dx.doi.org/10.1107/S002188980600731X[Crossref]
• [23] R.D. Shannon, Acta. Cryst. A. 32, 751 (1976) http://dx.doi.org/10.1107/S0567739476001551[Crossref]
• [24] H.W. Gu, S.X. Xiao, H.Y. Xiao, H.Y. Xiao, Y. Xiao, A.T. Li, X.L. Hu, Q.G. Li, Ind. Eng. Chem. Res. 51, 4797 (2012) http://dx.doi.org/10.1021/ie202891s[Crossref]
• [25] P. Koczoń, J.Cz. Dobrowolski, W. Lewandowski, A.P. Mazurek, J. Mol. Struct. 655, 89 (2003) http://dx.doi.org/10.1016/S0022-2860(03)00247-3[Crossref]
• [26] V.L. Dorofeev, Pharm. Chem. J. 38, 12 (2004)
• [27] O. Khan, Molecular Magnets (VCH Publishers Inc., New York, 1993)

Identifiers

DOI

10.2478/s11532-013-0366-5