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Journal
2011 | 9 | 5 | 910-916
Article title

Structure-reactivity relationships in organosilicon chemistry revisited

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EN
Abstracts
EN
Available quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative to the carbon chemistry values, the scale of steric constants E S (Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects, steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis can be employed in investigations of organosilicon reactions along with other methods. [...]
Publisher
Journal
Year
Volume
9
Issue
5
Pages
910-916
Physical description
Dates
published
1 - 10 - 2011
online
24 - 7 - 2011
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0075-x
Identifiers
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