Structure-reactivity relationships in organosilicon chemistry revisited

• Authors: Anu Ploom , Ants Tuulmets , Jaak Järv
• Languages of publication: EN

Abstracts

EN

Available quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative to the carbon chemistry values, the scale of steric constants E S (Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects, steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis can be employed in investigations of organosilicon reactions along with other methods. [...]

Keywords

EN

Correlation analysis; Linear free energy relationships; Silicon compounds; Substituent effects

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 5
• Pages: 910-916

Dates

published

1 - 10 - 2011

online

24 - 7 - 2011

Contributors

author

Anu Ploom

author

Ants Tuulmets

• Institute of Chemistry, University of Tartu, Tartu, 50411, Estonia

author

Jaak Järv

• Institute of Chemistry, University of Tartu, Tartu, 50411, Estonia

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Identifiers

DOI

10.2478/s11532-011-0075-x