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Journal
2011 | 9 | 4 | 610-618
Article title

Synthesis, UV/vis spectra and electrochemical characterisation of arylthio and styryl substituted ferrocenes

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Languages of publication
EN
Abstracts
EN
Two series of substituted ferrocenes were synthesised using either the Horner-Wadsworth-Emmons reaction or monolithiation of ferrocene. The series consist of arylthio- and styryl-ferrocenes with different substituents in the para position of the aryl rings of the systems. The electronic communication was investigated by comparing the substituent effects in absorption spectroscopy and in cyclic voltammetry. A small substituent effect was found in the electronic transitions of the styryl substituted ferrocenes. The oxidation of the ferrocene derivatives showed clear substituent effects as illustrated by the linear Hammett plots. The effect was shown to be an order of magnitude larger in the arylthio-systems than in the styryl systems. It is suggested that the reason behind the large effect is a direct sulfur-iron orbital overlap. [...]
Publisher

Journal
Year
Volume
9
Issue
4
Pages
610-618
Physical description
Dates
published
1 - 8 - 2011
online
4 - 6 - 2011
Contributors
  • Nano-Science Center and Department of Chemistry, University of Copenhagen, 2100, København Ø, Denmark, TJS@chem.ku.dk
  • Nano-Science Center and Department of Chemistry, University of Copenhagen, 2100, København Ø, Denmark
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-011-0040-8
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