Synthesis, UV/vis spectra and electrochemical characterisation of arylthio and styryl substituted ferrocenes

• Authors: Thomas Sørensen , Merete Nielsen
• Languages of publication: EN

Abstracts

EN

Two series of substituted ferrocenes were synthesised using either the Horner-Wadsworth-Emmons reaction or monolithiation of ferrocene. The series consist of arylthio- and styryl-ferrocenes with different substituents in the para position of the aryl rings of the systems. The electronic communication was investigated by comparing the substituent effects in absorption spectroscopy and in cyclic voltammetry. A small substituent effect was found in the electronic transitions of the styryl substituted ferrocenes. The oxidation of the ferrocene derivatives showed clear substituent effects as illustrated by the linear Hammett plots. The effect was shown to be an order of magnitude larger in the arylthio-systems than in the styryl systems. It is suggested that the reason behind the large effect is a direct sulfur-iron orbital overlap. [...]

Keywords

EN

Electrochemistry; Lithiation; Ligand effects; Ferrocene

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 4
• Pages: 610-618

Dates

published

1 - 8 - 2011

online

4 - 6 - 2011

Contributors

author

Thomas Sørensen

• Nano-Science Center and Department of Chemistry, University of Copenhagen, 2100, København Ø, Denmark

author

Merete Nielsen

• Nano-Science Center and Department of Chemistry, University of Copenhagen, 2100, København Ø, Denmark

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Identifiers

DOI

10.2478/s11532-011-0040-8