pH impact on the sol-gel preparation of calcium hydroxyapatite, Ca10(PO4)6(OH)2, using a novel complexing agent, DCTA

• Authors: Irma Bogdanoviciene , Kaia Tőnsuaadu , Valdek Mikli , Inga Grigoraviciute-Puroniene , Aldona Beganskiene , Aivaras Kareiva
• Languages of publication: EN

Abstracts

EN

Aqueous sol-gel chemistry routes - based on ammonium hydrogen phosphate as the phosphorus precursor, calcium acetate monohydrate as the source of calcium ions, and 1,2-diaminocyclohexanetetraacetic acid monohydrate (DCTA) as the complexing agent - have been used to prepare calcium hydroxyapatite (HA). The sol-gel process was performed in aqueous solution at different pH values followed by calcination of the dry precursor gels for 5 h at 1000°C. Phase transformations, composition, and structural changes in the polycrystalline samples were studied by thermoanalytical methods (TG/DTA), infrared spectroscopy (IR), X-ray powder diffraction analysis (XRD), and scanning electron microscopy (SEM). It was shown that pH adjustment has significant impact on the apatite formation process and on the morphology and phase purity of the ceramic samples.

Keywords

EN

Calcium hydroxyapatite; Aqueous sol-gel process; DCTA; Structural features

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2010
• Volume: 8
• Issue: 6
• Pages: 1323-1330

Dates

published

1 - 12 - 2010

online

8 - 10 - 2010

Contributors

author

Irma Bogdanoviciene

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Kaia Tőnsuaadu

• Laboratory of Inorganic Materials, Tallinn University of Technology, 19086, Tallinn, Estonia

author

Valdek Mikli

author

Inga Grigoraviciute-Puroniene

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Aldona Beganskiene

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

author

Aivaras Kareiva

• Department of General and Inorganic Chemistry, Vilnius University, LT-03225, Vilnius, Lithuania

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Identifiers

DOI

10.2478/s11532-010-0113-0