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EN
PM10 samples were collected during winter and summer seasons at two different sites in the area of Trieste (Italy). The content of As, Cd, Cr, Mn, Ni, Pb and V in the PM10 samples was determined by inductively coupled plasma-mass spectrometry, with the purpose of evaluating the relevance of PM10 inhalation as a route of human exposure to these elements. The results showed that the ambient air concentration of the aforementioned elements were below the limits or target values for both sites and season. Site and season-specific correlation analysis was conducted for the identification of metals with similar origin: very good correlation for the couple Ni-V was found in both sites and seasons, showing the influence of combustion of heavy oils in PM10 composition. The inter-site and seasonal variability of both PM10 and metal concentrations were examined. A stronger impact by the vehicular traffic on the PM10 and metal concentrations was found for the urban site in both seasons. Because of the great importance of the “Bora” wind on the local climate, variability of PM10 and toxic elements concentration with wind were analysed, allowing determination of the effect of wind on dilution of the pollutants for the urban site during both seasons. [...]
EN
The mean and standard deviation of pH value in the present study during the wet and dry seasons varied from 6.21±0.22 - 5.75±0.41. The mean and standard deviation of EC in the current study ranges between 219.15±12.20 - 193.30±14.81 μS/cm for wet and dry seasons which are found to be in line with the WHO standard used. The mean and standard deviation of DO for this study during the wet and dry seasons were found to be 10.03±0.58 - 6.47±0.41 (mg/L). TDS for wet and dry seasons ranges from 374.79 ±5.33 - 121.65 ±6.33 mg/L. The nitrate [9.05 ±1.08 - 8.09 ±1.57], sulphate [3.91 ±0.51 – 3.73 ±0.46] and phosphate [82.78 ±3.86 - 81.76±3.32] in this present study for wet and dry season were all found to be below the standard. The Hazard quotient via ingestion and Hazard quotient via dermal has a reduction in the order of lead > nickel > iron > manganese > copper > zinc and lead > zinc > nickel > copper > iron > manganese > cadmium, in cooperation in children and adults in wet season, correspondingly. The Hazard quotient via ingestion and Hazard quotient via dermal has a decrease in the following order of nickel > lead > manganese > copper > iron > zinc and lead >zinc > nickel > copper > manganese > iron > for both children and adults in dry season, respectively. Lead possess carcinogenic risk for the inhabitants of this area due to the value of the carcinogenic risk n wet season of 4.05E-4 in adult and 1.55E-3 in children, in dry season of 2.57E-4 in adult and 9.88E-4 in children, against the standard set by the USEPA of 10-6 – 10-4. The surface water is not suitable for drinking as seen by the high water quality index of > 300. Lead possess carcinogenic risk for the inhabitants.
EN
The inhibitive action of phytic acid (PA) on Q235 mild steel corrosion in 1 M HCl environment was investigated using electrochemical techniques. Polarization results revealed PA to be a mixed- type inhibitor in 1 M HCl environment, while impedance results provide evidence of adsorption of the PA species on the corroding metal surface. The adsorption of PA obeyed Langmuir adsorption isotherm. Scanning electron microscopy (SEM), atomic force microscopy (AFM) and Fourier transform infrared spectroscopy (FTIR) studies all revealed the formation of a protective film adsorbed on the steel surface.
EN
The aim of this study was to find correlations between several studied elements and analyzed materials as well as the application and validation of an analytical method to determine trace elements in hair, fingernails and toenails of healthy volunteers (normal concentration). The method developed covers washing, mineralization and ICP-MS determination of 10 elements (Ca, Cd, Co, Cr, Cu, Fe, Mg, Ni, Pb and Zn) in hair and nails. Concentrations of the selected elements in hair, fingernails and toenails were measured for 24 women and 18 men. Furthermore, a chemometric approach (Principal Component Analysis, PCA) was employed to evaluate the correlations between concentrations of the elements in hair and nails and between these materials. Until now PCA has not been frequently applied in handling and interpretation of the results of analysis of biological materials. However, the results of the present investigation show the high potential of PCA in extraction of valuable information from analytical measurements. Additionally, PCA has become a useful tool for visualization of the obtained results. Moreover, the cluster analysis (CA) was used to group the samples according to gender, taking into account two different groups of elements: essential and toxic. [...]
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