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2010 | 15 | 79 - 86

Article title

EFFECT OF pH VALUE AND ADSORBENT CONCENTRATION ON THE EFFECTIVENESS OF ADSORPTION ONTO CHITIN AND CHITOSAN

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EN

Abstracts

EN
The study was aimed at determining the effectiveness of reactive dye RB5 removal in the adsorption process onto chitin and chitosan as affected by the quantity of an adsorbent and pH value of the solution. The experiment was conducted at two concentrations of a sorbent, i.e. 1 and 5 mg d.m./dm3 and at three values of the reaction, i.e. pH 3.0, pH 5.0, and pH 9.0. The kinetics of RB5 sorption onto chitin and chitosan was described with the use of Langmuir model. In the case of both adsorbents examined, the highest adsorption capacity was achieved at pH 3.0 and adsorbent concentration of 1 g d.m./dm3. Increasing pH value up to pH 5.0 and 9.0 and adsorbent concentration in the sample from 1 to 5 g d.m./dm3 caused a decrease in the quantity of dye absorbed.

Keywords

Contributors

  • Department of Environmental Protection Engineering University of Warmia and Mazury in Olsztyn
  • Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul. Warszawska 117, 10–720 Olsztyn, Poland
  • Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul. Warszawska 117, 10–720 Olsztyn, Poland

References

  • Karcher S., Kornmüller A., Jekel M.; (2001) Cucubituril for water treatment. Part I; Solubility of cucubituril and sorption of reactive dyes. Water Res 35(14) pp. 3309-3314.
  • Annadurai G., Lee J. F.; (2008) Equilibrium studies on the adsorption of acid dye into chitin. Environ Chem Lett 6, pp. 77–81.
  • Rinaudo M.; (2006) Chitin and chitosan: Properties and applications. Progress in Polymer Science 31, pp. 603–632.
  • Ravi Kumar M. N. V.; (2000) A review of chitin and chitosan applications. Reactive & Functional Polymers 46, pp. 1-27.
  • Chiou M. S., Li H. Y.; (2002) Equilibrium and kinetic modeling of adsorption of reactive dye on cross-linked chitosan beads. J Hazard Mater B93, 233-248.
  • Klimiuk E., Filipkowska U., Wojtasz–Pająk A.; (2003) The effect of ph and chitin preparation on adsorption of reactive dyes. Polish J Environ Studies 12(5), pp. 575-588.
  • Filipkowska U.; (2006) Efficiency of reactive dyes adsorption onto chitin and chitosan beads. In Jaworska M. M. (ed.), Progress on Chemistry and Application of Chitin and Its Derivatives, Monograph 11, pp. 53-60.
  • Filipkowska U.; (2007) Adsorption and desorption efficiency of Black 8 and Black 5 onto Chitin and Chitosan. In Jaworska M. M. (ed.), Progress on Chemistry and Application of Chitin and Its Derivatives, Monograph 12, pp. 57-63.
  • Hasan M., Ahmad A. L.; (2008) Hameed B H, Adsorption of reactive dye onto cross-linked chitosan/oil palm ash composite beads. Chem. Eng. J. 136, pp. 164–172.
  • Al.-Degs Y. S., El-Barghouthi M. I., El-Sheikh A. H., Walker G. M.; (2008) Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon. Dyes Pigments 77, pp. 16-23.

Document Type

article

Publication order reference

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bwmeta1.element.psjd-55f81f19-f2fb-4bc2-ad87-bc1a75894dad
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