Synthesis and Characterization of Phenol/Urea/Formaldehyde and Clay Composites

• Authors: Ç. Doğar , A. Gürses , S. Köktepe , F. Mindivan , K. Güneş , S. Aktürk
• Languages of publication: EN

Abstracts

EN

Recently, so-called "phenol-formaldehyde-urea resins", which are generally made only by mechanical blending of UF resin and alkaline type PF resins, have been used as adhesives for the manufacturing of wood products. Faster curing PF resins can be also prepared by the addition of urea during or after the resin synthesis to yield co-condensed phenol-urea-formaldehyde (PUF) resins. In this study, resin/clay composites were prepared by in situ polymerization of phenol(18.2%)-urea(36.3%)-formaldehyde(45.5%) (PUF) with the various ratios of organoclay (7.69-45.45%) and colored organoclay (3.22-20.0%). The objective of our work is the investigation of the effect of addition of both organoclay and colored organoclay at different ratios on the textural characteristics. The composites are characterized by X-ray diffraction, Fourier transform infrared spectroscopy techniques and using high resolution transmission electron microscopy images of the samples. It was found that clay layers exfoliated in the resin matrix.

Keywords

EN

81.05.Qk; 82.35.Gh; 82.35.Lr

Discipline

• 82.35.Lr: Physical properties of polymers
• 82.35.Gh: Polymers on surfaces; adhesion(see also 68.35.Np Adhesion in surfaces and interfaces)
• 81.05.Qk: Reinforced polymers and polymer-based composites

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 125
• Issue: 2
• Pages: 374-378

Dates

published

2014-02

Contributors

author

Ç. Doğar

• Faculty of Education, Department of Science Education, Erzincan University, 24030, Erzincan, Turkey

author

A. Gürses

• Faculty of Kazım Karabekir Education, Department of Chemistry, Atatürk University, 25240, Erzurum, Turkey

author

S. Köktepe

• Faculty of Education, Department of Science Education, Erzincan University, 24030, Erzincan, Turkey

author

F. Mindivan

• Faculty of Kazım Karabekir Education, Department of Chemistry, Atatürk University, 25240, Erzurum, Turkey

author

K. Güneş

• Faculty of Kazım Karabekir Education, Department of Chemistry, Atatürk University, 25240, Erzurum, Turkey

author

S. Aktürk

• Faculty of Sciences, Department of Chemistry, Muğla University, 48000, Muğla, Turkey

References

• 1. G. He, N. Yan, doi: 10.1016/J.polymer.2004.08.019, Polymer 45, 6813 (2004)
• 2. B. Tomita, M. Ohyama, C.-Y. Hse, Holzforschung 48, 522 (1994)
• 3. D. Fan, J.-Z. Li, J. Chang, Eur. Polym. J. 45, 2849 (2009)
• 4. G. He, B. Rield, J. Polym. Sci. Pol. Phys. 41, 1929 (2003)
• 5. L.B. Paiva, A.R. Morales, R. Francisco, V. Díaz, Appl. Clay Sci. 42, 8 (2008)
• 6. I. Poljansek, U. Sebenik, M. Krajnc, doi: 10.1002/app.22161, J. Appl. Polym. Sci. 99, 2016 (2006)
• 7. Z. Wu, C. Zhou, R. Qı, Polymer Compos. 23, 634 (2002)
• 8. A. Pizzi, Handbook of Adhesive Technology, ch: Natural Phenolic Adhesives I: Tannin, 2nd ed., Eds.: A. Pizzi, K.L. Mittal, Dekker, New York 2003, p. 573
• 9. S.M. Lee, Ph.D. Thesis, Mississippi State University, 2003
• 10. H. Lei, G. Du, A. Pizzi, A. Celzard, doi: 10.1002/app.28359, J. Appl. Polym. Sci. 109, 2442 (2008)
• 11. S. Samarzija-Jovanović, V. Jovanović, S. Konstantinović, G. Marković, M. Marinović-Cincovic, doi: 10.1007/s10973-010-1143-8, J. Therm. Anal. Calorim. 104, 1159 (2011)
• 12. B. Tomita, C.-Y. Hse, Int. J. Adhesion Adhesives 18, 69 (1997)
• 13. H. Dalir, R.F. Farahani, M. Lévesque, D. Therriault, InTech, New York 2011
• 14. I. Polijansek, M. Krajnc, Acta Chim. Slov. 52, 238 (2005)
• 15. A. Gürses, M. Yalçın, Ç. Doğar, Water Air Soil Poll. 146, 297 (2003)
• 16. G. Rivero, A. Vázquez, L. Manfredi, doi: 10.1002/app.30574, J. Appl. Polym. Sci. 114, 32 (2009)
• 17. D. Wang, G. Chang, Y. Chen, Polym. Degr. Stab. 93, 125 (2008)

Identifiers

DOI

10.12693/APhysPolA.125.374