Novel catalytic method synthesis of calix[4]pyrroles using Preyssler and Wells-Dawson heteropolyacids

• Authors: Ali Gharib , Manouchehr Jahangir , J. Scheeren
• Languages of publication: EN

Abstracts

EN

A catalytic synthesis of calix[4]pyrroles and N-confused calix[4]pyrroles by reaction of dialkyl or cycloalkyl ketones with pyrrole was performed using Preyssler, sodium30-tungsto pentaphosphate, [NaP5W30O110]14- and Wells-Dawson heteropolyacids as acidic catalysts. The process occurred under mild, eco-friendly and environmental friendly conditions and as a reusable, green catalyst at room temperature for 6 hours. The results showed that the yield for this synthesis is excellent with the use of Preyssler and Wells-Dawson type tungstophosphoric heteropolyacid, H6[P2W18O62], catalysts. The synthesis reaction of calix[4]pyrroles and N-confused calix[4]pyrroles was developed using different solvents and the best yields were obtained in chloroform.

Keywords

EN

Calix[4]pyrrole; Heteropolyacid; Preyssler; Wells-Dawson; Catalysis; N-confused calix[4]pyrrole

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2011
• Volume: 13
• Issue: 2
• Pages: 70-73

Dates

published

1 - 1 - 2011

online

16 - 6 - 2011

Contributors

author

Ali Gharib

author

Manouchehr Jahangir

• Department of Chemistry, Islamic Azad University, Mashhad, IRAN

author

J. Scheeren

• Cluster for Molecular Chemistry, Department of Organic Chemistry, Radboud University Nijmegen, The Netherlands

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Identifiers

DOI

10.2478/v10026-011-0027-4