Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

• Authors: Agnieszka Wróblewska , Grzegorz Wójtowicz
• Languages of publication: EN

Abstracts

EN

The influence of technological parameters on the transformation of 1-butene-3-ol (1B3O) to bis(3-methyl-1-propene) ether (2×1B3O ether) and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether (1B3Ox1,2EB3O ether) over the TS-2 catalyst was presented. The reaction was performed in a glass reactor at atmospheric pressure and in methanol medium (protic solvent). The optimum conditions of 2×1B3O ether and 1B3Ox1,2EB3O ether obtaining were established by the mathematical method of experiments design (rotatable-uniform design) and after the analyses of the layer drawings.

Keywords

EN

bis(3-methyl-1-propene) ether; 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether; TS-2; hydrogen peroxide; epoxidation in liquid phase

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2010
• Volume: 12
• Issue: 3
• Pages: 66-71

Dates

published

1 - 1 - 2010

online

27 - 9 - 2010

Contributors

author

Agnieszka Wróblewska

• Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Grzegorz Wójtowicz

• Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

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Identifiers

DOI

10.2478/v10026-010-0037-7