Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst - the new and friendly method of 2,3-epoxybutane-1-ol synthesis

• Authors: Agnieszka Wróblewska , Anna Fajdek , Eugeniusz Milchert
• Languages of publication: EN

Abstracts

EN

Epoxidation of crotyl alcohol (CA) with 30 wt% hydrogen peroxide over Ti-MWW catalyst has been studied with methanol as a solvent and at autogenic pressure. The influence of temperature in the range of 20-120°C, the molar ratio of CA/H2O2 1:1-5:1, methanol concentration 5-90 wt%, Ti-MWW catalyst concentration 0.0-5.0 wt% and the reaction time 5-300 min have been studied. The main product of CA epoxidation is 2,3-epoxybutane-1-ol (2,3EB1O), a compound with many applications.

Keywords

EN

Ti-MWW; crotyl alcohol epoxidation; 2,3-epoxybutane-1-ol

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2010
• Volume: 12
• Issue: 2
• Pages: 57-61

Dates

published

1 - 1 - 2010

online

9 - 7 - 2010

Contributors

author

Agnieszka Wróblewska

• Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Anna Fajdek

• Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Eugeniusz Milchert

• Institute of Organic Chemical Technology, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

References

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Identifiers

DOI

10.2478/v10026-010-0019-9