Characteristic of physicochemical properties of Pd/MgO catalysts used in the hydrodechlorination process with CCI4

• Authors: Jacek Góralski , Bożena Szczepaniak , Jacek Grams , Waldemar Maniukiewicz , Tadeusz Paryjczak
• Languages of publication: EN

Abstracts

EN

The aim of this paper was to investigate the physicochemical properties of palladium catalyst containing basic support MgO which was used in hydrodechlorination reaction with carbon tetrachloride. In order to characterize the investigated sample the catalyst was put to tests of XRD, TOF - SIMS, TG-DTA-MS and TPRH2 measurements, activity tests were also performed. The XRD and TPR results demonstrated the presence of PdOxCly species whose decomposition takes place above 700°C. The calcination of the Pd/MgO catalyst at 700°C resulted in the transformation of PdOxCly to PdO.

Keywords

EN

palladium catalyst; basic properties of MgO; hydrodechlorination; CCl4

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2007
• Volume: 9
• Issue: 3
• Pages: 77-80

Dates

published

1 - 1 - 2007

online

6 - 11 - 2007

Contributors

author

Jacek Góralski

• Institute of General and Ecological Chemistry, Technical University of Łódź, ul. Żeromskiego 116, 90-924 Łódź, Poland

author

Bożena Szczepaniak

• Institute of General and Ecological Chemistry, Technical University of Łódź, ul. Żeromskiego 116, 90-924 Łódź, Poland

author

Jacek Grams

• Institute of General and Ecological Chemistry, Technical University of Łódź, ul. Żeromskiego 116, 90-924 Łódź, Poland

author

Waldemar Maniukiewicz

• Institute of General and Ecological Chemistry, Technical University of Łódź, ul. Żeromskiego 116, 90-924 Łódź, Poland

author

Tadeusz Paryjczak

• Institute of General and Ecological Chemistry, Technical University of Łódź, ul. Żeromskiego 116, 90-924 Łódź, Poland

References

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Identifiers

DOI

10.2478/v10026-007-0059-y