Application of poly (N-phenylethanolamine) modified
MWCNTs as a new sorbent for solid-phase extraction of
trace palladium ions in soil and water samples

• Authors: Mohammad Behbahani , Akbar Bagheri , Tayebeh Gorji , Mohammad Reza Nabid , Roya Sedghi , Hossein Abdi Oskooie , Majid M. Heravi
• Languages of publication: EN

Abstracts

EN

This paper describes, a new, sensitive, and low cost solid-phase extraction
(SPE) method using a poly(N-phenylethanolamine) /multi-walled carbon
nanotubes (MWCNTs) nanocomposite for extraction, pre-concentration,
and flame atomic absorption spectrometric (FAAS) determination of trace
level palladium in distilled water, tap water, Caspian sea water, Persian
Gulf water, spring water, lake water and soil samples, as well as real
samples. The poly(N-phenylethanolamine)/MWCNTs nanocomposite
were characterized using Fourier Transform-infrared (FT-IR) spectroscopy,
thermo-gravimetric analysis (TGA) and scanning electron microscopy
(SEM). Factors affecting the pre-concentration of palladium, including
sample pH, flow rate, and type and volume of eluent, were investigated.
The effect of interfering ions and break through volume on the separation
and determination of palladium ions was also determined. The maximum
sorbent capacity of the poly (N-phenylethanolamine)/MWCNTs
nanocomposite was calculated to be 101.5 mg g−1. The pre-concentration
factor, relative standard deviation, and limit of detection of the method
were found to be 150, 2.8% (n=10), and 0.09 ng mL−1, respectively. The
presented method was compared to certified reference materials, and
finally, the presented technique was applied to different matrices spiked
with 5 ng mL−1 of analyte.

Keywords

EN

poly(N-phenylethanolamine); multi-walled carbon nanotubes; Solid-phase extraction; Preconcentration; Palladium; Flame atomic absorption spectrometry

• Publisher: De Gruyter Open
• Journal: Sample Preparation
• Year: 2013
• Volume: 1
• Pages: 10-17

Dates

online

10 - 06 - 2013

accepted

16 - 03 - 2013

received

16 - 11 - 2012

Contributors

author

Mohammad Behbahani

• Department of Chemistry,
  Shahid Beheshti University, G.C,
  1983963113, Tehran, Iran

author

Akbar Bagheri

• Department of Chemistry,
  Shahid Beheshti University, G.C,
  1983963113, Tehran, Iran

author

Tayebeh Gorji

• Department of Chemistry,
  Islamic Azad University,
  Central Tehran Branch, Tehran, Iran

author

Mohammad Reza Nabid

• Department of Chemistry,
  Shahid Beheshti University, G.C,
  1983963113, Tehran, Iran

author

Roya Sedghi

• Department of Chemistry,
  Shahid Beheshti University, G.C,
  1983963113, Tehran, Iran
• Department of Chemistry,
  School of Science, Azzahra University,
  Vanak, Tehran, Iran

author

Hossein Abdi Oskooie

• Department of Chemistry,
  School of Science, Azzahra University,
  Vanak, Tehran, Iran

author

Majid M. Heravi

• Department of Chemistry,
  School of Science, Azzahra University,
  Vanak, Tehran, Iran

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Identifiers

DOI

10.2478/sampre-2013-0002