Electokinetic and adsorption properties of different titanium dioxides at the solid/solution interface

• Authors: Svitlana Khalameida , Ewa Skwarek , Wladyslaw Janusz , Volodymyr Sydorchuk , Roman Leboda , Jadwiga Skubiszewska-Zięba
• Languages of publication: EN

Abstracts

EN

Six samples of titanium dioxide of different phase compositions and specific surface areas have been characterized by XRD, Raman-and FTIR spectroscopy, adsorption of nitrogen, electrophoresis. Adsorption of Zn(II) ions at the TiO2/NaCl aqueous solution interface as well as the effect of adsorption on the structure of electrical double layer have been studied. The influence of ionic strength, pH and presence of ions on the adsorption of Zn(II) ions at the TiO2/NaCl solution interface have also been investigated. The zeta potential, surface charge density, parameters of adsorption edge pH50% and ΔpH10–90% for different concentrations of basic electrolyte have been determined. Studied unpurified samples showed lower values of isoelectric point pHiep compared with literature data due to the presence of anion impurities. The antibate dependence between pHiep values and particle size has been established. Adsorption of Zn(II) ions using monophase samples is completed at a lower pH than for the biphase TiO2. Appearance of the point CR3 is associated with the charge turnover from positive to negative at high values of pH and formation of Zn(OH)2.

Keywords

EN

Mono- and biphase TiO2 ; Electrical double layer; Surface charge density; Zeta potential; Adsorption of Zn (II) ions

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 11
• Pages: 1194-1205

Dates

published

1 - 11 - 2014

online

15 - 5 - 2014

Contributors

author

Svitlana Khalameida

• Institute for Sorption and Problems of Endoecology of NAS of Ukraine

author

Ewa Skwarek

• Maria Curie Skłodowska University

author

Wladyslaw Janusz

• Maria Curie Skłodowska University

author

Volodymyr Sydorchuk

• Institute for Sorption and Problems of Endoecology of NAS of Ukraine

author

Roman Leboda

• Maria Curie Skłodowska University

author

Jadwiga Skubiszewska-Zięba

• Maria Curie Skłodowska University

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Identifiers

DOI

10.2478/s11532-014-0568-5