Quinine sulfate: a pharmaceutical product as effective corrosion inhibitor for carbon steel in hydrochloric acid solution

• Authors: Adriana Samide , Bogdan Tutunaru
• Languages of publication: EN

Abstracts

EN

Quinine sulfate dihydrate (QNS), IUPAC name: (8S,9R)-6-methoxy-4-quinolenyl-5-vinyl-2-quinuclidinyl methanol sulfate dihydrate, was tested as corrosion inhibitor for carbon steel in 1.5 mol L−1 HCl solution using the potentiodynamic polarization and the electrochemical impedance spectroscopy (EIS) associated with UV-Vis spectrophotometry. The electrochemical results showed that, the inhibition efficiency (IE) increased with the increase in QNS concentration, reaching a maximum value of 93.35±0.25%. The polarization resistance (R
p) followed the same trend, obtaining the highest value of 659.7 Ω cm2, while the corrosion current density (i
corr) reached the lowest level of 195 µA cm−2. The action mechanism of QNS was proposed considering the ability of quinine (QN) to be adsorbed on the metal surface via the lone pairs of electrons from hydroxyl oxygen atom, and/or from quinoline and quinuclidinic nitrogens. The occurrence of the complexes between inhibitor and iron ions was considered an additional process, which may contribute to protective layer formation. The Temkin adsorption isotherm was found as the best fitting for the degree of surface coverage (θ) values. In order to elucidate the mechanism of protective layer formation, the free energy of adsorption (ΔG
o
ads) value was calculated. This indicates that the inhibitor acts by chemical adsorption on the steel surface.

Keywords

EN

Quinine sulfate; Corrosion inhibition; Carbon steel; Electrochemical measurements; Adsorption

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 9
• Pages: 901-908

Dates

published

1 - 9 - 2014

online

1 - 5 - 2014

Contributors

author

Adriana Samide

• University of Craiova

author

Bogdan Tutunaru

• University of Craiova

References

• [1] H.D. Lece, K.C. Emregul, O. Atakol, Corros. Sci. 50, 1460 (2008) http://dx.doi.org/10.1016/j.corsci.2008.01.014[Crossref]
• [2] E. Samiento-Bustos, J.G. Gonzalez Rodriguez, J. Uruchurtu, G. Dominguez-Patino, V.M. Salinas-Bravo, Corros. Sci. 50, 2296 (2008) http://dx.doi.org/10.1016/j.corsci.2008.05.014[Crossref]
• [3] M. Sahin, G. Gece, F. Karci, S. Bilgic, J. Appl. Electrochem. 38, 809 (2008) http://dx.doi.org/10.1007/s10800-008-9517-3[Crossref]
• [4] G. Gece, Corros. Sci. 50, 2981 (2008) http://dx.doi.org/10.1016/j.corsci.2008.08.043[Crossref]
• [5] W.A. Badawy, K.M. Ismail, A.M. Fathi, Electrochim. Acta 51, 4182 (2006) http://dx.doi.org/10.1016/j.electacta.2005.11.037[Crossref]
• [6] M. Abdallah, E.A. Helal, A.S. Fouda, Corros. Sci. 48, 1639 (2006) http://dx.doi.org/10.1016/j.corsci.2005.06.020[Crossref]
• [7] A.S. Fouda, M. Abdallah, A. Attia, Chem. Eng. Commun. 197, 1091 (2010) http://dx.doi.org/10.1080/00986440903412944[Crossref]
• [8] L. Adamczyk, A. Pietrusiak, H. Bala, Cent. Eur. J. Chem. 10, 1657 (2012) http://dx.doi.org/10.2478/s11532-012-0082-6[Crossref]
• [9] O. Olivares, N.V. Likhanova, B. Gomez, J. Navarrete, M.E. Llanos-Serrano, E. Arce, J.M. Hallen, Appl. Surf. Sci. 252, 2894 (2006) http://dx.doi.org/10.1016/j.apsusc.2005.04.040[Crossref]
• [10] A. Popova, E. Sokolova, S. Raicheva, M. Christov, Corros. Sci. 45, 33 (2003) http://dx.doi.org/10.1016/S0010-938X(02)00072-0[Crossref]
• [11] J.O’M Bockris, A.K.N. Reddy, Modern Electrochemistry, 2nd edition (Kluwer Academic Publishers, New York, 2004) vol. 2B
• [12] G. Broussard, O. Bramantit, F.M. Marchese, Occup. Med. 47, 337 (1997) http://dx.doi.org/10.1093/occmed/47.6.337[Crossref]
• [13] S.H. Kumar, S. Karthikeyan, J. Mater. Environ. Sci. 3, 925 (2012)
• [14] N. Vaszilcsin, V. Ordodi, A. Borza, Int. J. Pharm. 431, 241 (2012) http://dx.doi.org/10.1016/j.ijpharm.2012.04.015[Crossref]
• [15] I. Ahamad, S. Khan, K.R. Ansari, M.A. Quraishi, J. Chem. Pharm. Res. 3, 703 (2011)
• [16] A. K. Singh, S.K. Shukla, M. Singh, M.A. Quraishi, Mat. Chem. Phys. 129, 68 (2011) http://dx.doi.org/10.1016/j.matchemphys.2011.03.054[Crossref]
• [17] N.O. Eddy, S.A. Odoemelam, P. Ekwumemgbo, Sci. Res. Essays 4, 33 (2009)
• [18] N.O. Eddy, S.A. Odoemelam, Adv. Nat. Appl. Sci. 2, 225 (2008)
• [19] S.K. Shukla, A.K. Singh, I. Ahamad, M.A. Quraishi, Mater. Lett. 63, 819 (2009) http://dx.doi.org/10.1016/j.matlet.2009.01.020[Crossref]
• [20] A. Samide, B. Tutunaru, C. Negrila, I. Trandafir, A. Maxut, Dig. J. Nanomater. Bios. 6, 663 (2011)
• [21] A. Samide, B. Tutunaru, C. Negrila, A. Dobritescu, J. Therm. Anal. Calorim. 110, 145 (2012) http://dx.doi.org/10.1007/s10973-011-2186-1[Crossref]
• [22] T. Arslan, F. Kandemirli, E.E. Ebenso, I. Love, H. Alemu, Corros. Sci. 51, 35 (2009) http://dx.doi.org/10.1016/j.corsci.2008.10.016[Crossref]
• [23] R. Solmaz, G. Kardas, B. Yazıcı, M. Erbil, Prot. Met. 41, 628 (2005) http://dx.doi.org/10.1007/s11124-005-0083-3[Crossref]
• [24] A.S. Ekop, N.O. Eddy, Aust. J. Basic Appl. Sci. 2, 1258 (2008)
• [25] N.O. Eddy, S.A. Odoemelam, A.J. Mbaba, Afr. J. Pure Appl. Chem. 2, 132 (2008)
• [26] A.K. Singh, M.A. Quraishi, Corros. Sci. 52, 152 (2010) http://dx.doi.org/10.1016/j.corsci.2009.08.050[Crossref]
• [27] A. Samide, J. Environ. Sci. Health A Tox. Hazard. Subst. Environ. Eng. 48, 159 (2013) http://dx.doi.org/10.1080/03601234.2012.716744[Crossref]
• [28] A.S. Fouda, H.A. Mostafa, H.M. El-Abbasy, J. Appl. Electrochem. 40, 163 (2010) http://dx.doi.org/10.1007/s10800-009-9992-1[Crossref]
• [29] R.A. Prabhu, A.V. Shanbhag, T.V. Venkatesha, J. Appl. Electrochem. 37, 491 (2007) http://dx.doi.org/10.1007/s10800-006-9280-2[Crossref]
• [30] S.K. Shukla, M.A. Quraishi, Mater. Chem. Phys. 120, 142 (2010) http://dx.doi.org/10.1016/j.matchemphys.2009.10.037[Crossref]
• [31] I. Naqvi, A.R. Saleemi, S. Naveed, Int. J. Electrochem. Sci. 6, 146 (2011)
• [32] I. Ahamad, M.A. Quraishi, Corros. Sci. 52, 651 (2010) http://dx.doi.org/10.1016/j.corsci.2009.10.012[Crossref]
• [33] S.K. Shukla, M.A. Quraishi, E.E. Ebenso, Int. J. Electrochem. Sci. 6, 2912 (2011)
• [34] X.H. Pang, W.J. Guo, W.H. Li, J.D. Xie, B.R. Hou, Sci. China Ser. B-Chem. 51, 928 (2008) http://dx.doi.org/10.1007/s11426-008-0099-z[Crossref]
• [35] E.E. Ebenso, I.B. Obot, L.C. Murulana, Int. J. Electrochem. Sci. 5, 1574 (2010)
• [36] R. Ahmad Dar, P.K. Brahman, S. Tiwari, K.S. Pitre, Colloid. Surf. B: Biointerf. 98, 72 (2012) http://dx.doi.org/10.1016/j.colsurfb.2012.04.035[Crossref]
• [37] M.I. Awad, J. Appl. Electrochem. 36, 1163 (2006) http://dx.doi.org/10.1007/s10800-006-9204-1[Crossref]
• [38] S. Joshi, D.D. Pant, J. Molec. Liq. 166, 49 (2012) http://dx.doi.org/10.1016/j.molliq.2011.11.012[Crossref]
• [39] B. Zerga, A. Attayibat, M. Sfaira, M. Taleb, B. Hammouti, M. Ebn Touhami, S. Radi, Z. Rais, J. Appl. Electrochem. 40, 1575 (2010) http://dx.doi.org/10.1007/s10800-010-0164-0[Crossref]
• [40] A. Samide, B. Tutunaru, J. Environ. Sci. Health A Tox. Hazard. Subst. Environ. Eng. 46, 1713 (2011) http://dx.doi.org/10.1080/10934529.2011.623972[Crossref]
• [41] A. Samide, B. Tutunaru, Chem. Biochem. Eng. Q 25, 299 (2011)
• [42] R. Hubel, K. Polborn, W. Beck, Eur. J. Inorg. Chem. 1999, 471 (1999) http://dx.doi.org/10.1002/(SICI)1099-0682(199903)1999:3<471::AID-EJIC471>3.0.CO;2-H
• [43] A.C. Tella, J.A. Obaleye, J. Nepal Chem. Soc. 25, 19 (2010) http://dx.doi.org/10.3126/jncs.v25i0.3280[Crossref]
• [44] A.P. Samide, I. Bibicu, Surf. Interface Anal. 40, 944 (2008) http://dx.doi.org/10.1002/sia.2825[Crossref]
• [45] A. Samide, B. Tutunaru, C. Ionescu, C. Tigae, A. Moanta, Int. J. Electrochem. Sci. 8, 3589 (2013)
• [46] Bùi Quang Cu, Nguyễn Thanh Hồng, Đỗ Thị Thu Huong, Vietnam Journal of Chemistry 43(2), 152 (2005)
• [47] J.A. Obaleye, A.C. Tella, R.O. Arise, Adv. in Nat. Appl. Sci. 3, 43 (2009)
• [48] N.A. Rey, K.C. dos Santos, M. Â. B. C. Menezes, A.S. Mangrich, E.C. Pereira-Maia, J. Braz. Chem. Soc. 17, 497 (2006) http://dx.doi.org/10.1590/S0103-50532006000300010[Crossref]
• [49] J.M. Tsangaris, T. A. Kabanos, Monatshefte für Chemie / Chemical Monthly, 113, 1393 (1982) http://dx.doi.org/10.1007/BF00808938[Crossref]
• [50] B. Zerga, B. Hammouti, M. Ebn Touhami, R. Touir, M. Taleb, M. Sfaira, M. Bennajeh, I. Forssal, Int. J. Electrochem. Sci. 7, 471 (2012)
• [51] A. Samide, E. Turcanu, I. Bibicu, Chem. Eng. Comm. 196, 1008 (2009) http://dx.doi.org/10.1080/00986440902797881[Crossref]
• [52] A. Samide, B. Tutunaru, Catalin Negrila, I. Prunaru, Spectrosc. Lett. 45, 55 (2012) http://dx.doi.org/10.1080/00387010.2011.598599[Crossref]
• [53] M.A. Migahed, Mater. Chem. Phy. 93, 48 (2005) http://dx.doi.org/10.1016/j.matchemphys.2005.02.003[Crossref]
• [54] H. Zarrok, S.S. Al-Deyab, A. Zarrouk, R. Salghi, B. Hammouti, H. Oudda, M. Bouachrine, F. Bentiss, Int. J. Electrochem. Sci. 7, 4047 (2012)
• [55] A. Moanta, A. Samide, C. Ionescu, B. Tutunaru, A. Dobritescu, A. Fruchier, V. Barragan-Montero, Int. J. Electrochem. Sci. 8, 780 (2013)

Identifiers

DOI

10.2478/s11532-013-0399-9