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Number of results

Journal

2014 | 12 | 9 | 953-961

Article title

New high-pressures vapor-liquid equilibrium data for the carbon dioxide + 2-methyl-1-propanol (isobutanol) binary system

Content

Title variants

Languages of publication

EN

Abstracts

EN
New vapor-liquid equilibria (VLE) data at 333.15, 343.15, and 353.15 K and pressures up to 130.0 bar are reported for the carbon dioxide + 2-methyl-1-propanol (isobutanol) system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSITM) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-1-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data.

Publisher

Journal

Year

Volume

12

Issue

9

Pages

953-961

Physical description

Dates

published
1 - 9 - 2014
online
1 - 5 - 2014

Contributors

author
  • University Politehnica of Bucharest
author
  • University Politehnica of Bucharest
author
  • University Politehnica of Bucharest

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0394-1
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