Application of Box-Behnken design with response surface methodology for modeling and optimizing ultrasonic oxidation of arsenite with H2O2

• Authors: Pengpeng Qiu , Mingcan Cui , Kyounglim Kang , Beomguk Park , Yonggyu Son , Eunkyung Khim , Min Jang , Jeehyeong Khim
• Languages of publication: EN

Abstracts

EN

A combined ultrasound (US)/H2O2 process was used to oxidize arsenite to arsenate, yielding a synergistic effect value of 1.26. This showed that the combined process could be an effective method of oxidizing arsenite, instead of using either ultrasonic or H2O2 oxidation processes. This combined process was successfully modeled and optimized using a Box-Behnken design with response surface methodology (RSM). The effects of the US power density, the initial concentration of arsenite, and the H2O2 concentration on the sonochemical oxidation efficiency of arsenite were investigated. Analysis of variance indicated that the proposed quadratic model successfully interpreted the experimental data with coefficients of determination of R
2 = 0.95 and adjusted R
2 = 0.91. Through this model, we can predict and control the oxidation efficiency under different conditions. Furthermore, the optimal conditions for the oxidation of arsenite were found to be a US power density of 233.26 W L−1, an initial arsenite concentration of 0.5 mg L−1, and an H2O2 concentration of 74.29 mg L−1. The predicted oxidation efficiency obtained from the RSM under the optimal conditions was 88.95%. A confirmation test of the optimal conditions verified the validity of the model, yielding an oxidation efficiency of 90.1%.

Keywords

EN

Sonochemical Oxidation; Synergy; Kinetics; Mathematical modeling

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 2
• Pages: 164-172

Dates

published

1 - 2 - 2014

online

27 - 11 - 2013

Contributors

author

Pengpeng Qiu

• Korea University

author

Mingcan Cui

• Korea University

author

Kyounglim Kang

• Korea University

author

Beomguk Park

• Korea University

author

Yonggyu Son

• Kumoh National Institute of Technology

author

Eunkyung Khim

• Korea University

author

Min Jang

• University of Malaya

author

Jeehyeong Khim

• Korea University

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Identifiers

DOI

10.2478/s11532-013-0360-y