Hydrogen bonding-based 3D supramolecular architecture of [Cu(CHA)2][TCM]·11H2O

• Authors: Mihaela Vlassa , Gheorghe Borodi , Cristian Silvestru , Mircea Vlassa
• Languages of publication: EN

Abstracts

EN

Reaction of Na4TCM (1) (H4TCM = tetra[4-(carboxyphenyl)oxamethyl]methane) with [Cu(CHA)](ClO4)2 (2)(CHA = 1,3,6,8,11,14-hexaaz atricyclo[12.2.1.1.8,11] octadecane) in a DMF-water mixture yields [Cu(CHA)]2[TCM] (3). Structural analysis of [Cu(CHA)]2[TCM]·11H2O (3·11H2O) by single crystal X-ray diffraction reveals strong copper-oxygen bonds between two complex cations and the tetraanion leading to a 3D coordination network (zwitterionic structure), consolidated through additional NH...O=C hydrogen bonding within the cation/anion association. The resulting coordination geometry around a copper atom is a distorted square pyramidal with an oxygen atom of the anionic ligand in the apical position. A 3D supramolecular network is developed in the crystal based only on NH...OC hydrogen bonds between the macrocyclic metallic tecton and the carboxylate groups of neighboring 3D coordinated (zwitterionic) moieties. The pseudotetrahedral TCM4− tetraanionic ligand induces a diamondoid architecture formed of large distorted adamantanoid cages. [...]

Keywords

EN

Coordination polymer; Flexible networks; Hydrogen bonding; Copper

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 1
• Pages: 14-24

Dates

published

1 - 1 - 2014

online

27 - 10 - 2013

Contributors

author

Mihaela Vlassa

• “Raluca Ripan” Institute of Research in Chemistry, Babeş-Bolyai University, 400294, Cluj-Napoca, Romania

author

Gheorghe Borodi

• National Institute for Research and Development of Isotopic and Molecular Technologies — INCDTIM, 400293, Cluj-Napoca, Romania

author

Cristian Silvestru

• Department of Chemistry, Center of Supramolecular Organic and Organometallic Chemistry, Babeş-Bolyai University, Faculty of Chemistry and Chemical Engineering, 400028, Cluj-Napoca, Romania

author

Mircea Vlassa

• Faculty of Chemistry and Chemical Engineering, Department of Chemistry, Babeş-Bolyai University, 400028, Cluj-Napoca, Romania

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Identifiers

DOI

10.2478/s11532-013-0350-0