Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results

Journal

2013 | 11 | 12 | 2058-2065

Article title

Shape memory polyurethanes based on recycled polyvinyl butyral. I. Synthesis and morphology

Content

Title variants

Languages of publication

EN

Abstracts

EN
Shape memory polyurethanes (SMPUs) were synthesized by 4,4′-diphenylmethane diisocyanate (MDI), hexane-1,6-diol (HD), polypropylene glycol (PPG), and recycled polyvinyl butyral (PVB). Dynamic mechanical analysis, differential scanning calorimetry and Fourier transformation infrared attenuated total reflection spectroscopy was used to characterize the poly (vinylbutyral-urethanes). Micro-phase domain separation of hard and soft segments and phase inversion were investigated. Increasing the hard segment content, i.e., average hard segment molecular weight, leads to an increase in the degree of micro-phase separation, hard domain order and crystallinity. The crystalline hard segment structures combined with the elastic nature of soft segment matrix provide enough physical and chemical crosslinks to have shape memory effect.

Publisher

Journal

Year

Volume

11

Issue

12

Pages

2058-2065

Physical description

Dates

published
1 - 12 - 2013
online
26 - 9 - 2013

Contributors

  • University of Applied Sciences Wildau, 15745, Wildau, Germany
  • University of Applied Sciences Wildau, 15745, Wildau, Germany
  • University of Chemical Technology and Metallurgy Sofia, 1756, Sofia, Bulgaria

References

  • [1] C. Liu, H. Qin, P.T. Mather, Journal of Materials Chemistry 17, 1543 (2007) http://dx.doi.org/10.1039/b615954k[Crossref]
  • [2] D. Ratna, J. Karger-Kocsis, Journal of Materials Science 43, 254 (2008) http://dx.doi.org/10.1007/s10853-007-2176-7[Crossref]
  • [3] R.J. Zdrahala, R.M. Gerkin, S.L. Hager, F.E. Critchfield, Journal of Materials Science 24, 2041 (1979)
  • [4] H.K. Lee, S.W. Ko, Journal of Applied Polymer Science 50, 1269 (1993) http://dx.doi.org/10.1002/app.1993.070500718[Crossref]
  • [5] G. Spathis, M. Niaounakis, E. Kontou, L. Apekis, P. Pissis, C. Christodoulides, Journal of Applied Polymer Science 54, 831 (1994) http://dx.doi.org/10.1002/app.1994.070540701[Crossref]
  • [6] R.P. Redman, Developments in Polyurethanes (Applied Science Publishers, London, 1978)
  • [7] R.F. Harris, M.D. Joseph, C. Davidson, C.D. Deporter, V.A. Dais, Journal of Applied Polymer Science 41, 509 (1990) http://dx.doi.org/10.1002/app.1990.070410305[Crossref]
  • [8] L.M. Leung, J.T. Koberstein, Macromolecules 19, 706 (1986) http://dx.doi.org/10.1021/ma00157a038[Crossref]
  • [9] J.T. Koberstein, R.S. Stein, Journal of Polymer Science Part B: Polymer Physics 21, 1439 (1983) http://dx.doi.org/10.1002/pol.1983.180210814[Crossref]
  • [10] W. Hu, J.T. Koberstein, Journal of Polymer Science Part B: Polymer Physics 32, 437 (1994) http://dx.doi.org/10.1002/polb.1994.090320304[Crossref]
  • [11] D.J. Martin, G.F. Meijs, G.M. Renwick, P.A. Gunatillake, S.J. McCarthy, Journal of Applied Polymer Science 60, 557 (1996) http://dx.doi.org/10.1002/(SICI)1097-4628(19960425)60:4<557::AID-APP9>3.0.CO;2-N[Crossref]
  • [12] A.K. Dhaliwal, J.N. Hay, Thermochimica Acta 391, 245 (2002) http://dx.doi.org/10.1016/S0040-6031(02)00187-9[Crossref]
  • [13] Y.M. Tsai, T.L. Yu, Y.H. Tseng, Polymer International 47, 445 (1998) http://dx.doi.org/10.1002/(SICI)1097-0126(199812)47:4<445::AID-PI82>3.0.CO;2-B[Crossref]
  • [14] C.C. Chang, K.S Chen, T.L. Yu, Y.S. Chen, C.L. Tsai, Y.H. Tseng, Polymer Journal 30, 1205 (1999) http://dx.doi.org/10.1295/polymj.31.1205[Crossref]
  • [15] C.B. Wang, S.L Cooper, Macromolecules 6, 775 (1983) http://dx.doi.org/10.1021/ma00239a014[Crossref]
  • [16] H. Tobushi, H. Hara, E. Yamada, S. Hayashi, Smart Materials and Structures 5, 483 (1996) http://dx.doi.org/10.1088/0964-1726/5/4/012[Crossref]
  • [17] T.K. Chen, J.Y. Chui, T.S. Shieh, Macromolecules 30, 5068 (1997) http://dx.doi.org/10.1021/ma9618639[Crossref]
  • [18] R. Bonart, L. Morbitzer, Kolloid -Zaitschrift und Zeitschrift für Polymere 241, 909 (1970) (in German) http://dx.doi.org/10.1007/BF02137395[Crossref]
  • [19] A. Schönhals, H. Goering, Ch. Schick, B. Frick, R. Zorn, European Physical Journal E 12, 173 (2003) http://dx.doi.org/10.1140/epje/i2003-10036-4[Crossref]
  • [20] C. S. Schollenberger, K. Dinbergs, Journal of Elastomers and Plastics 11, 58 (1979)
  • [21] R. Bonart, Die Angewandte Makromolekulare Chemie 58/59, 259 (1977) (in German) http://dx.doi.org/10.1002/apmc.1977.050580112[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0331-3
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.