Preparation and conductivities of polyacrylic acid/polyvinylimidazole grafted and ungrafted iron oxide nanocomposite polymer electrolytes

• Authors: Mehmet Senel , Hüseyin Kavas , Mehmet Tutgun , Abdulhadi Baykal
• Languages of publication: EN

Abstracts

EN

Nanocomposites of Polyacrylic acid/polyvinylimidazole (PAA/PVI) with grafted and ungrafted iron oxide nanoparticles were prepared by a Reflux method. The Fe3O4 nanoparticles with 10 nm average diameter were synthesized by controlled co-precipitation and silanization of Si-PVI on Fe3O4 was used to obtain the grafted ones. Grafting becomes important at composites of less PVI that cause drastic decreases in AC conductivity. The content of PVI has important effects on the conductivity mechanism of these composites. The effect of grafting and Polyacrylic acid/polyvinylimidazole molar ratio on the conduction mechanism were studied. The conduction mechanism of iron oxide nanocomposites can be adjusted by changing molar ratio of Polyacrylic acid/polyvinylimidazole and grafting of Fe3O4NPs. [...]

Keywords

EN

Nanostructures; Chemical synthesis; Impedance spectroscopy; Electrical properties; Dielectric properties

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 11
• Pages: 1768-1779

Dates

published

1 - 11 - 2013

online

25 - 8 - 2013

Contributors

author

Mehmet Senel

• Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500, Istanbul, Turkey

author

Hüseyin Kavas

• Department of Physics Engineering, Faculty of Sciences, Istanbul Medeniyet University, 34720, Istanbul, Turkey

author

Mehmet Tutgun

• Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500, Istanbul, Turkey

author

Abdulhadi Baykal

• Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500, Istanbul, Turkey

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Identifiers

DOI

10.2478/s11532-013-0318-0