An experimental and theoretical study of the polar [2+3] cycloaddition reactions between 1-chloro-1-nitroethene and (Z)-C-aryl-N-phenylnitrones

• Authors: Radomir Jasiński , Maria Mikulska , Andrzej Barański
• Languages of publication: EN

Abstracts

EN

Abstract Kinetic studies and B3LYP/6-31g(d) calculations indicate the polar nature of [2+3] cycloadditions between 1-chloro-1-nitroethene to (Z)-C-aryl-N-phenylnitrones. This is clearly confirmed by the activation parameters and the substituent and solvent effects. Graphical abstract [...]

Keywords

EN

[2+3] cycloaddition; Nitrone; Kinetic study; DFT calculations; Global nucleophilicity

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 9
• Pages: 1471-1480

Dates

published

1 - 9 - 2013

online

29 - 6 - 2013

Contributors

author

Radomir Jasiński

• Institute of Organic Chemistry and Technology, Cracow University of Technology, 31155, Cracow, Poland

author

Maria Mikulska

• Institute of Organic Chemistry and Technology, Cracow University of Technology, 31155, Cracow, Poland

author

Andrzej Barański

• Institute of Organic Chemistry and Technology, Cracow University of Technology, 31155, Cracow, Poland

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Identifiers

DOI

10.2478/s11532-013-0276-6