Debromination of 2,4,6-tribromophenol coupled with biodegradation

• Authors: Tomáš Weidlich , Lubomír Prokeš , Dagmar Pospíšilová
• Languages of publication: EN

Abstracts

EN

The application effect of aluminium and their alloys and mixtures with nickel was studied for the complete hydrodebromination of 2,4,6-tribromophenol (TBP) to phenol in aqueous NaOH solution at room temperature. It was found that the Raney Al-Ni alloy can rapidly transform TBP to phenol. Removal efficiency of 25 mM TBP solution in aqueous NaOH (15 g L−1) solution at the end of 1h reaction was 100% using 4 g L−1 Al-Ni. The hydrodebromination is accompanied by the dissolution of aluminium and formation of soluble Al(OH)4−1 anions under these reaction conditions. After completion of the hydrodebromination reaction removal of the dissolved metals was achieved by precipitation of appropriate hydroxides by adjustment of the pH value and filtration, the filtrate was treated with Pseudomonas or Rhodococcus bacterial strains to degrade dissolved phenol. The combined application of both (chemical-biological) treatments produced degradations of 100% of aromatic compounds. [...]

Keywords

EN

Dehalogenation; Raney Al-Ni alloy; Metal removal; Pseudomonas; Rhodococcus

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 6
• Pages: 979-987

Dates

published

1 - 6 - 2013

online

28 - 3 - 2013

Contributors

author

Tomáš Weidlich

• Institute of Environmental and Chemical Engineering, Faculty of Chemical Technology, University of Pardubice, 532 10, Pardubice, Czech Republic

author

Lubomír Prokeš

author

Dagmar Pospíšilová

• Department of Biotechnology, Institute of Chemical Technology Prague, 166 28, Prague 6, Czech Republic

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Identifiers

DOI

10.2478/s11532-013-0231-6