Research on thermal decomposition of trinitrophloroglucinol salts by DSC, TG and DVST

• Authors: Rui Liu , Tonglai Zhang , Li Yang , Zunning Zhou , Xiaochun Hu
• Languages of publication: EN

Abstracts

EN

The thermal decomposition of the four nitrogen-rich salts of ammonia (NH4), aminoguanidine (AG), carbohydrazide (CHZ) and 5-aminotetrazo (ATZ) based on trinitrophloroglucinol (H3TNPG) was investigated using the differential scanning calorimetry (DSC), thermogravity (TG), and dynamic vacuum stability test (DVST). DSC and TG methods research the complete decomposition, while DVST method researches the very early reaction stage. The peak temperatures of DSC curves are consistent with the temperatures of maximum mass loss rates of TG curves. The apparent activation energies of these H3TNPG-based salts obtained by DSC and DVST have the same regularity, i.e., (ATZ)(H2TNPG)·2H2O 2O 4(H2TNPG) 2TNPG). The thermal stability order is (ATZ)(H2TNPG)·2H2O 2O 2TNPG) 4(H2TNPG), which was evaluated by DVST according to the evolved gas amount of thermal decomposition. DVST can monitor the real-time temperature and pressure changes caused by thermal decomposition, dehydration, phase transition and secondary reaction, and also evaluate the thermal stability and kinetics. [...]

Keywords

EN

Thermal decomposition; H3TNPG-based salts; Kinetic parameters; Thermal stability; DVST

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 5
• Pages: 774-781

Dates

published

1 - 5 - 2013

online

27 - 2 - 2013

Contributors

author

Rui Liu

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, China

author

Tonglai Zhang

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, China

author

Li Yang

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, China

author

Zunning Zhou

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, China

author

Xiaochun Hu

• The 3rd Department, Institute of Chemical Defense, Beijing, 102205, China

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Identifiers

DOI

10.2478/s11532-013-0205-8