Extraction properties of β-aminophosphine oxides towards lanthanides and alkaline earth metals

• Authors: Ekaterina Matveeva , Elena Sharova , Alexander Turanov , Vasilii Karandashev , Irina Odinets
• Languages of publication: EN

Abstracts

EN

The investigation of the extraction properties of a series of polyoligodentate β-aminophosphine oxides 1–8 bearing from one to six phosphine oxide groups in a molecule towards Ln(III) and alkaline earth metals ions from neutral media has revealed that, using common diluents, the extraction efficiency increases with an increase of a number of P=O functions in a ligand. The addition of ionic liquid, namely 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([bmim][NTf2]), significantly increasing the extraction efficiency and application of IL concentration of 0.05 M (in 1,2-dichloroethane) providing the maximum recovery of metal ions with Lu/La separation factor reaching up to 91. Hexapodal tris[bis(2-diphenylphosphorylethyl)aminoethyl]amine 8 demonstrates the highest extraction under all conditions applied and the separation factor for U and Eu of this compound exceeded 103. [...]

Keywords

EN

β-aminophosphine oxides; Lanthanides(III); Alkaline earth metals; Ionic liquids; Liquid-liquid extraction

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 6
• Pages: 1933-1941

Dates

published

1 - 12 - 2012

online

21 - 9 - 2012

Contributors

author

Ekaterina Matveeva

• A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

author

Elena Sharova

• A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

author

Alexander Turanov

• Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia

author

Vasilii Karandashev

• Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, Chernogolovka, 142432, Russia

author

Irina Odinets

• A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

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Identifiers

DOI

10.2478/s11532-012-0124-0