Equilibrium, kinetic, and thermodynamic studies of Basic Blue 9 dye sorption on agro-industrial lignocellulosic materials

• Authors: Daniela Suteu , Carmen Zaharia , Teodor Malutan
• Languages of publication: EN

Abstracts

EN

The sorptive potential of some lignocellulosic agro-industrial wastes (sunflower seed shells and corn cob) for Basic Blue 9 cationic dye removal from aqueous solutions was examined using the batch technique. The Freundlich, Langmuir, and Dubinin-Radushkevich isotherm models were used in order to determine the quantitative parameters of sorption. The Langmuir isotherm model indicated a maximum sorption capacity for these materials in the range of 40–50 mg dye per g (25°C), slightly higher for corn cob than for sunflower seed shells. The values of the thermodynamic parameters showed that the retention of cationic dye is a spontaneous and endothermic process. The application of pseudo-first order and pseudo-second order intraparticle diffusion models, and a Boyd - Reichenberg model for kinetic data interpretation suggested that sorption of Basic Blue 9 dye onto the studied materials is a process where both surface sorption and intraparticle diffusion contributed to the rate-limiting step. These lignocellulosic wastes can be used with good efficiency for dye removal from aqueous effluents. [...]

Keywords

EN

Lignocellulosic wastes; Corn cob; Basic Blue 9 dye; Sorption; Sunflower seed shell

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 6
• Pages: 1913-1926

Dates

published

1 - 12 - 2012

online

21 - 9 - 2012

Contributors

author

Daniela Suteu

• Department of Organic Biochemical and Food Engineering, Faculty of Chemical Engineering and Environmental Protection, “Gheorghe Asachi” Technical University of Iassy, 700050, Iassy, Romania

author

Carmen Zaharia

• Department of Environmental Engineering and Management, Faculty of Chemical Engineering and Environmental Protection, “Gheorghe Asachi” Technical University of Iassy, 700050, Iassy, Romania

author

Teodor Malutan

• Department of Natural and Synthetic Polymers, Faculty of Chemical Engineering and Environmental Protection, “Gheorghe Asachi” Technical University of Iassy, 700050, Iassy, Romania

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Identifiers

DOI

10.2478/s11532-012-0122-2