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Number of results

Journal

2012 | 10 | 5 | 1495-1499

Article title

Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water

Content

Title variants

Languages of publication

EN

Abstracts

EN
From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1·Na+(nb) 1·C+ (nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, cation TRIS+, hydrazinium, hydroxylammonium; 1 = benzo-18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1·C+ cationic complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: triethanolammonium + [...]

Publisher

Journal

Year

Volume

10

Issue

5

Pages

1495-1499

Physical description

Dates

published
1 - 10 - 2012
online
21 - 7 - 2012

Contributors

  • Faculty of Environmental Sciences, Czech University of Life Sciences, 165 21, Prague 6, Czech Republic
author
  • Department of Analytical Chemistry, Institute of Chemical Technology, 166 28, Prague 6, Czech Republic
  • Nuclear Research Institute, 250 68, Řež, Czech Republic

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-012-0052-z
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