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Number of results

Journal

2012 | 10 | 4 | 1218-1222

Article title

Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen

Content

Title variants

Languages of publication

EN

Abstracts

EN
A new organometallic complex coupling photoactive coumarin to a diironhexacarbonyl unit has been successfully prepared and its composition and electronic structure confirmed by elemental and spectroscopic analyses. Emission spectral analysis of the complex reveals photoinduced intramolecular electron transfer from coumarin to the iron-carbonyl moiety. The compound is electrochemically reduced at −1.24 V vs. Fc/Fc+. This reduction is irreversible, attesting to the instability of the complex. Electrochemical evolution of hydrogen in the presence of the complex has been studied and results are discussed. [...]

Publisher

Journal

Year

Volume

10

Issue

4

Pages

1218-1222

Physical description

Dates

published
1 - 8 - 2012
online
29 - 5 - 2012

Contributors

author
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA
author
  • Department of Physical Sciences, Arkansas Tech University, Russellville, Arkansas, 72801, USA

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-012-0048-8
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