Glassy carbon and boron doped glassy carbon electrodes for voltammetric determination of linuron herbicide in the selected samples

• Authors: Jelena Đorđević , Ana Kalijadis , Ksenija Kumrić , Zoran Jovanović , Zoran Laušević , Tatjana Trtić-Petrović
• Languages of publication: EN

Abstracts

EN

In this study the application of home-made unmodified (GC) and bulk modified boron doped glassy carbon (GCB) electrodes for the voltammetric determination of the linuron was investigated. The electrodes were synthesized with a moderate temperature treatment (1000°C). Obtained results were compared with the electrochemical determination of the linuron using a commercial glassy carbon electrode (GC-Metrohm). The peak potential (E p ) of linuron oxidation in 0.1 mol dm−3 H2SO4 as electrolyte was similar for all applied electrodes: 1.31, 1.34 and 1.28 V for GCB, GC and GC-Metrohm electrodes, respectively. Potential of linuron oxidation and current density depend on the pH of supporting electrolyte. Applying GCB and GC-Metrohm electrodes the most intensive electrochemical response for linuron was obtained in strongly acidic solution (0.1 mol dm−3 H2SO4). Applying the boron doped glassy carbon electrode the broadest linear range (0.005–0.1 µmol cm−3) for the linuron determination was obtained. The results of voltammetric determination of the linuron in spiked water samples showed good correlation between added and found amounts of linuron and also are in good agreement with the results obtained by HPLC-UV method. This appears to be the first application of a boron doped glassy carbon electrode for voltammetric determination of the environmental important compounds. [...]

Keywords

EN

Linuron; Glassy carbon electrode; Boron doped glassy carbon electrode; Differential pulse voltammetry

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1271-1279

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

Jelena Đorđević

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

author

Ana Kalijadis

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

author

Ksenija Kumrić

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

author

Zoran Jovanović

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

author

Zoran Laušević

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

author

Tatjana Trtić-Petrović

• Laboratory of Physics, Vinča Institute of Nuclear Sciences, University of Belgrade, 11001, Belgrade, Serbia

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Identifiers

DOI

10.2478/s11532-012-0042-1