Synthesis, crystal structure, spectroscopic and thermal investigations of neodymium(III) biphenyl-4,4′-dicarboxylate framework

• Authors: Renata Łyszczek , Liliana Mazur
• Languages of publication: EN

Abstracts

EN

The three-dimensional complex {[Nd(bpdc)1.5(DMF)]·1.4DMF}n (DMF=N,N′-dimethylformamide, bpdc=biphenyl-4,4′-dicarboxylate) was synthesized using the solvothermal method. The crystal structure of the neodymium(III) complex has been determined by single-crystal X-ray diffraction method at 100(2) K. The polymeric structure consists of neodymium polyhedra bridged by bpdc ligands. Eight-coordinated Nd(III) atoms are surrounded by seven oxygen atoms from six bpdc moieties and one oxygen atom from the DMF molecule. The 3D structure of the complex contains two types of channels occupied by DMF molecules. Thermal analysis revealed that DMF molecules are lost in a stepwise manner. The infrared spectrum confirmed full deprotonation of acid and presence of DMF molecules in the structure. [...]

Keywords

EN

Crystal structure; Coordination polymer; Infrared spectra; TG-FTIR

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 4
• Pages: 1165-1174

Dates

published

1 - 8 - 2012

online

29 - 5 - 2012

Contributors

author

Renata Łyszczek

• Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska Univeristy, 20-031, Lublin, Poland

author

Liliana Mazur

• Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska Univeristy, 20-031, Lublin, Poland

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Identifiers

DOI

10.2478/s11532-012-0035-0