1,4-bis-(3-hydroxy-4-oxo-4H-chromen-2-yl)-benzene (bis-flavonol): synthesis, spectral properties and principle possibility of the excited state double proton transfer reaction

• Authors: Denis Svechkarev , Andrey Doroshenko , Dmitry Kolodezny
• Languages of publication: EN

Abstracts

EN

Synthesis and systematic investigation of the spectral-luminescent properties of “bis-flavonol” {1,4-bis-(3-hydroxy-4-oxo-4H-chromen-2-yl)-benzene} were performed. Hypothetical possibility for the double excited-state proton transfer reaction in bis-flavonol is discussed based on both quantum-chemical modeling and experimental data. Consecutive S1*-state transfer of the two protons of the title molecule is shown to be energetically unfavorable, however, still preserving a possibility for the concerted double proton transfer in the excited dienol form.

Keywords

EN

3-hydroxychromones; ESIPT; Double proton transfer; Multi-banded fluorescence; Multiparametric fluorescent probes

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 1
• Pages: 205-215

Dates

published

1 - 2 - 2012

online

24 - 11 - 2011

Contributors

author

Denis Svechkarev

• Kharkov V. N. Karazin National University

author

Andrey Doroshenko

• Kharkov V. N. Karazin National University

author

Dmitry Kolodezny

• Kharkov V. N. Karazin National University

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Identifiers

DOI

10.2478/s11532-011-0127-2