N-Tris[(2-aminoethyl)-2-(diphenylphosphoryl) acetamide)] - novel CMPO tripodand: synthesis, extraction studies and luminescent properties of lanthanide complexes

• Authors: Elena Sharova , Oleg Artyushin , Alexander Turanov , Vasilii Karandashev , Svetlana Meshkova , Zoya Topilova , Irina Odinets
• Languages of publication: EN

Abstracts

EN

A ligand system containing three carbamoylmethylphosphine oxide (CMPO) moieties attached to a tripodal platform with a central nitrogen atom has been synthesized for metal complexation and extraction from neutral and nitric acid solutions. Liquid-liquid extractions performed for Ln(III), both from neutral and acidic media, show excellent extraction properties which exceeded those for the known mono- and di-CMPO derivatives as well as the related tripodands. A considerable enhancement of the DLn values was observed in the presence of IL ([bmim][Tf2N]) in the organic phase towards lanthanide ions from 3M HNO3 solutions. The protonation of the central amine nitrogen atom of the ligand 1 in the acidic media provides also the effective extraction of the perrhenate anionic complexes. The europium complexes formed by mono- and tris-CMPO ligands in the solid state, as well as Eu(III) and Tb(III) complexes generated in solutions, possess intensive luminescence at 300K

Keywords

EN

Carbamoylmethylphosphine oxides; Lanthanides(III); Ionic liquids; Extraction; Luminescence

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2012
• Volume: 10
• Issue: 1
• Pages: 146-156

Dates

published

1 - 2 - 2012

online

24 - 11 - 2011

Contributors

author

Elena Sharova

• Russian Academy of Sciences

author

Oleg Artyushin

• Russian Academy of Sciences

author

Alexander Turanov

• Russian Academy of Sciences

author

Vasilii Karandashev

• Russian Academy of Sciences

author

Svetlana Meshkova

• National Academy of Sciences of Ukraine

author

Zoya Topilova

• National Academy of Sciences of Ukraine

author

Irina Odinets

• Russian Academy of Sciences

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Identifiers

DOI

10.2478/s11532-011-0124-5