Influence of activated carbon modifications on their catalytic activity in methanol and ethanol conversion reactions

• Authors: Jadwiga Jasińska , Beata Krzyżyńska , Mieczysław Kozłowski
• Languages of publication: EN

Abstracts

EN

Activated carbons containing different surface functionalities have been investigated as catalysts in conversion reactions of ethanol and methanol. These carbon materials were prepared from Polish brown coal by chemical activation with potassium hydroxide and modified by the oxidation or reaction with ammonia or chlorine. The main process upon ethanol decomposition was its dehydrogenation, while in the process of methanol decomposition only a few samples were catalytically active, and the only product was dimethyl ether (a product of dehydration). [...]

Keywords

EN

Dehydration; Dehydrogenation; Alcohols; Activated carbon; Catalytic activity

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 5
• Pages: 925-931

Dates

published

1 - 10 - 2011

online

24 - 7 - 2011

Contributors

author

Jadwiga Jasińska

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland

author

Beata Krzyżyńska

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland

author

Mieczysław Kozłowski

• Faculty of Chemistry, Adam Mickiewicz University, 60-780, Poznań, Poland

References

• [1] G.S. Szymański, G. Rychlicki, Carbon 31, 247 (1993) http://dx.doi.org/10.1016/0008-6223(93)90028-9[Crossref]
• [2] J. Bedia, R. Ruiz-Rosas, J. Rodríguez-Mirasol, T. Cordero, J. Catal. 271, 33 (2010) http://dx.doi.org/10.1016/j.jcat.2010.01.023[Crossref]
• [3] M.A. Aramendía, V. Boráu, I.M. García, C. Jiménez, A. Marinas, J.M. Marinas, A. Porras, F.J. Urbano, Appl. Catal. A Gen. 184, 115 (1999) http://dx.doi.org/10.1016/S0926-860X(99)00096-4[Crossref]
• [4] C. Lahousse, J. Bachelier, J.C. Lavalley, H. Lauron-Pernot, A.M. Le Govic, J. Mol. Catal. 87, 329 (1994) http://dx.doi.org/10.1016/0304-5102(93)E0232-6[Crossref]
• [5] G. Zazdrozna, E. Souvage, J. Kornatowski, J. Catal. 208, 270 (2002) http://dx.doi.org/10.1006/jcat.2002.3611[Crossref]
• [6] D. Zhang, R. Wang, X. Yang Catal. Lett. 124, 384 (2008) http://dx.doi.org/10.1007/s10562-008-9481-x[Crossref]
• [7] T. Zaki, J. Colloid. Interf. Sci. 284, 606 (2005) http://dx.doi.org/10.1016/j.jcis.2004.10.048[Crossref]
• [8] M. Xu, D.W. Goodman, A. Bhattacharyya, Appl. Catal. A Gen. 149, 303 (1997) http://dx.doi.org/10.1016/S0926-860X(96)00276-1[Crossref]
• [9] A.I. Ahmed, S.A. El-Hakam, S.E. Samra, A.A. El-Khouly, A.S. Khder, Colloid Surfaces A 317, 62 (2008) http://dx.doi.org/10.1016/j.colsurfa.2007.09.043[Crossref]
• [10] A.A.A. El-Raady, N.E. Fouad, M.A. Mohamed, S.A. Halawy, Monatsh. Chem. 133, 1351 (2002)
• [11] I. Takahara, M. Saito, M. Inaba, K. Murata, Catal. Lett. 105, 249 (2005) http://dx.doi.org/10.1007/s10562-005-8698-1[Crossref]
• [12] I. Takahara, M. Saito, H. Matsuhashi, M. Inaba, K. Murata, Catal. Lett. 113, 82 (2007) http://dx.doi.org/10.1007/s10562-007-9025-9[Crossref]
• [13] X. Zhang, R. Wang, X. Yang, F. Zhang, Micropor. Mesopor. Mater. 116, 210 (2008) http://dx.doi.org/10.1016/j.micromeso.2008.04.004[Crossref]
• [14] T. Tsoncheva, R. Nickolov, D. Mehandjiev, React. Kinet. Catal. Lett. 72, 383 (2001) http://dx.doi.org/10.1023/A:1010532004888[Crossref]
• [15] T. Tsoncheva, S. Vankova, D. Mehandjiev, React. Kinet. Catal. Lett. 80, 383 (2003) http://dx.doi.org/10.1023/B:REAC.0000006149.99996.5d[Crossref]
• [16] T. Tsoncheva, S. Vankova, D. Mehandjiev, Fuel 82, 755 (2003) http://dx.doi.org/10.1016/S0016-2361(02)00366-6[Crossref]
• [17] T. Tsoncheva, S. Vankova, O. Bozhkov, D. Mehandjiev, J. Mol. Catal. A Chem. 225, 245 (2005) http://dx.doi.org/10.1016/j.molcata.2004.09.013[Crossref]
• [18] S. Vankova, T. Tsoncheva, D. Mehandjiev, Catal. Commun. 5, 95 (2004) http://dx.doi.org/10.1016/j.catcom.2003.11.019[Crossref]
• [19] D. Paneva, T. Tsoncheva, E. Manova, I. Mitov, T. Ruskov, Appl. Catal. A Gen. 267, 67 (2004) http://dx.doi.org/10.1016/j.apcata.2004.02.024[Crossref]
• [20] C. Moreno-Castilla, M.A. Alvarez-Merino, F. Carrasco-Marín, React. Kinet. Catal. Lett. 71, 137 (2000) http://dx.doi.org/10.1023/A:1010358921525[Crossref]
• [21] F. Lefebvre, P. Dupont, A. Auroux, React. Kinet. Catal. Lett. 55, 3 (1995) http://dx.doi.org/10.1007/BF02075827[Crossref]
• [22] J. Zawadzki, B. Azambre, O. Heintz, A. Krztoń, J. Weber, Carbon 38, 509 (2000) http://dx.doi.org/10.1016/S0008-6223(99)00130-X[Crossref]
• [23] G.S. Szymański, G. Rychlicki, A.P. Terzyk, Carbon 32, 265 (1994) http://dx.doi.org/10.1016/0008-6223(94)90189-9[Crossref]
• [24] G.C. Grunewald, D.S. Drago J., Am. Chem. Soc. 113, 1636 (1991) http://dx.doi.org/10.1021/ja00005a029[Crossref]
• [25] F. Carrasco-Marín, A. Mueden, C. Moreno-Castilla, J. Phys. Chem. B 102, 9239 (1998) http://dx.doi.org/10.1021/jp981861l[Crossref]
• [26] C. Moreno-Castilla, M.V. López-Ramón, F. Carrasco-Marín, Carbon 38, 1995 (2000) http://dx.doi.org/10.1016/S0008-6223(00)00048-8[Crossref]
• [27] C. Moreno-Castilla, F. Carrasco-Marón, C. Parejo-Pérez, M.V. López Ramón, Carbon 39, 869 (2001) http://dx.doi.org/10.1016/S0008-6223(00)00192-5[Crossref]
• [28] E. Jasińska, B. Krzyżyńska, M. Kozłowski, Catal. Lett. 125, 145 (2008) http://dx.doi.org/10.1007/s10562-008-9536-z[Crossref]
• [29] W. Shen, Z. Li, Y. Liu, Recent Patents on Chemical Engineering 1, 27 (2008) http://dx.doi.org/10.2174/1874478810801010027[Crossref]
• [30] J.L. Figueiredo, M.F.R. Pereira, M.M.A. Freitas, J.J.M. Orfao, Carbon 37, 1379 (1999) http://dx.doi.org/10.1016/S0008-6223(98)00333-9[Crossref]
• [31] J. Trawczyński, S. Suppan, C. Sayag, G. Djéga-Mariadassou, Fuel Process. Technol. 77–78, 317 (2002) http://dx.doi.org/10.1016/S0378-3820(02)00057-7[Crossref]
• [32] P. Chingombe, B. Saha, R.J. Wakeman, Carbon 43, 3132 (2005) http://dx.doi.org/10.1016/j.carbon.2005.06.021[Crossref]
• [33] J.W. Shim, S.J. Park, S.K. Ryu, Carbon 39, 1635 (2001) http://dx.doi.org/10.1016/S0008-6223(00)00290-6[Crossref]
• [34] B.K. Pradhan, N.K. Sandle, Carbon 37, 1323 (1999) http://dx.doi.org/10.1016/S0008-6223(98)00328-5[Crossref]
• [35] J. Przepiórski, M. Skrodzewicz, A.W. Morawski, Appl. Surf. Sci. 225, 235 (2004) http://dx.doi.org/10.1016/j.apsusc.2003.10.006[Crossref]
• [36] E. Papirer, R. Lacroix, J.-B. Donnet, G. Nansé, P. Fioux, Carbon 33, 63 (1995) http://dx.doi.org/10.1016/0008-6223(94)00111-C[Crossref]
• [37] G.S. Szymański, Z. Karpiński, S. Biniak, A. Świątkowski, Carbon 40, 2627 (2002) http://dx.doi.org/10.1016/S0008-6223(02)00188-4[Crossref]
• [38] A.F. Pérez-Cadenas, F.J. Maldonado-Hódar, C. Moreno-Castilla, Carbon 41, 473 (2003) http://dx.doi.org/10.1016/S0008-6223(02)00353-6[Crossref]

Identifiers

DOI

10.2478/s11532-011-0078-7