Self-assembled hydrogen-bonded coordination networks in two copper(II) carboxylates with 4-pyridylmethanol

• Authors: Jaroslava Maroszová , Jan Moncol , Zdeňka Padělková , Reijo Sillanpää , Tadeusz Lis , Marian Koman
• Languages of publication: EN

Abstracts

EN

The crystal and molecular structure of [Cu(nif)2(4-PM)2]·CH3OH (1) and [Cu(2-Clbz)2(4-PM)2(H2O)] (2), (where nif = niflumate anion, 2-Clbz = 2-chlorobenzoate anion and 4-PM is the 4-pyridylmethanol), have been determinated by X-ray crystallography. The Cu2+ cation in (1), is coordinated by two pairs of oxygen atoms from asymmetric bidentate niflumate anions and by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands in trans position forming an extremely elongated bipyramid. The Cu2+ cation in (2), is coordinated by a pair of oxygen atoms from monodentate 2-chlorobenzoate anions, further by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands and finally by a water oxygen atom forming a tetragonal-pyramidal coordination polyhedron. The molecules of both complexes in crystal structures are linked by O-H…O hydrogen bonds, which created a three-dimensional hydrogen-bonding networks. The Π-Π stacking interactions are also observed in crystal structures of complex 2. The spectral properties (IR and electronic spectra) of both complexes were also investigated.

Keywords

EN

Copper complexes; Carboxylates; Supramolecular chemistry; Hydrogen bonds; Crystal structure

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 3
• Pages: 453-459

Dates

published

1 - 6 - 2011

online

22 - 3 - 2011

Contributors

author

Jaroslava Maroszová

• Slovak University of Technology

author

Jan Moncol

• Slovak University of Technology

author

Zdeňka Padělková

• University of Pardubice

author

Reijo Sillanpää

• University of Jyväskylä

author

Tadeusz Lis

• University of Wroclaw

author

Marian Koman

• Slovak University of Technology

References

• [1] K. Merz, V. Vasylyeva, CrystEngComm 12, 3989 (2010) http://dx.doi.org/10.1039/c0ce00237b[Crossref]
• [2] L. Brammer, Chem. Soc. Rev. 33, 476 (2004) http://dx.doi.org/10.1039/b313412c[Crossref]
• [3] D. Braga, F. Grepioni, Acc. Chem. Res. 33, 601 (2000) http://dx.doi.org/10.1021/ar990143u[Crossref]
• [4] G.R. Desiraju, J. Chem. Soc., Dalton Trans. 3745 (2000)
• [5] A.M. Beatty, Coord. Chem. Rev. 246, 131 (2003) http://dx.doi.org/10.1016/S0010-8545(03)00120-6[Crossref]
• [6] A.M. Beatty, CrystEngComm 3, 243 (2001) http://dx.doi.org/10.1039/b109127c[Crossref]
• [7] C. Aakeröy, A.M. Beatty, Aust. J. Chem. 54, 409 (2001) http://dx.doi.org/10.1071/CH01133[Crossref]
• [8] D. Burrows, Struct. Bonding 108, 55 (2004)
• [9] D. Burrows, C.W. Chan, M.M. Chowdhry, J.E. McGrady, M.D.P. Mingos, Chem. Soc. Rev. 329 (1995).
• [10] N.N. Hoang, F. Valach, M. Melník, Acta Cryst. C49, 467 (1993)
• [11] J. Moncol, M. Múdra, P. Lönnecke, M. Koman, M. Melník, J. Chem. Cryst. 34, 423 (2004) http://dx.doi.org/10.1023/B:JOCC.0000035382.59831.ee[Crossref]
• [12] T.C. Stamatatos, D. Foguet-Albiol, S.P. Perlepes, C.P. Raptopoulou, A. Terzis, C.S. Patrickios, G. Christou, A.J. Tasiopoulos, Polyhedron 25, 1737 (2006) http://dx.doi.org/10.1016/j.poly.2005.11.019[Crossref]
• [13] R. Murugavel, S. Kuppuswamy, R. Boomishankar, A. Steiner, Angew. Chem. Int. Ed. 45, 5536 (2006) http://dx.doi.org/10.1002/anie.200601704[Crossref]
• [14] F.J. Ramos-Lima, O. Vrana, A.G. Quiroga, C. Navarro-Ranninger, A. Halamikova, H. Rybnickova, L. Hejmalova, V. Bravec, J. Med. Chem. 49, 2640 (2006) http://dx.doi.org/10.1021/jm0602514[Crossref]
• [15] J. Moncol, J. Maroszová, M. Koman, M. Melník, M. Valko, M. Mazur, T. Lis, J. Coord. Chem. 61, 3740 (2008) http://dx.doi.org/10.1080/00958970802146031[Crossref]
• [16] J. Moncol, B. Kaliňaková, J. Švorec, M. Kleinová, M. Koman, D. Hudecová, M. Melník, M. Mazúr, M. Valko, Inorg. Chem. Acta 357, 3211 (2004) http://dx.doi.org/10.1016/j.ica.2004.03.043[Crossref]
• [17] I. Ucar, I. Bulut, A. Bulut, A. Karadag, Struct. Chem. 20, 825 (2009) http://dx.doi.org/10.1007/s11224-009-9475-3[Crossref]
• [18] J. Moncol, P. Segľa, D. Mikloš, M. Mazúr, M. Melník, T. Głowiak, M. Valko, M. Koman, Polyhedron 25, 1561 (2006) http://dx.doi.org/10.1016/j.poly.2005.10.029[Crossref]
• [19] J. Kavalírová, Z. Vasková, J. Maroszová, J. Moncol, M. Koman, T. Lis, M. Mazur, D. Valigura, Z. Anorg. Allg. Chem. 636, 589 (2010) http://dx.doi.org/10.1002/zaac.200900356[Crossref]
• [20] P. Stachová, D. Valigura, M. Koman, T. Głowiak, Acta Cryst. E61, m994 (2005)
• [21] M. Múdra, J. Moncol, J. Švorec, M. Melník, P. Lönnecke, T. Głowiak, R. Kirmse, Inorg. Chem. Commun. 6, 1259 (2003) http://dx.doi.org/10.1016/S1387-7003(03)00226-0[Crossref]
• [22] F. Valach, M. Tokarčík, P. Kubinec, M. Melník, L. Macášková, Polyhedron 16, 1461 (1997) http://dx.doi.org/10.1016/S0277-5387(97)86511-4[Crossref]
• [23] J. Moncol, D. Mikloš, P. Segľa, M. Koman, T. Lis, Acta Cryst. E64, m440 (2008)
• [24] A.L. Abuhijleh, J. Khalaf, Eur. J. Med. Chem. 45, 3811 (2010) http://dx.doi.org/10.1016/j.ejmech.2010.05.031[Crossref]
• [25] J. Moncol, M. Koman, M. Melník, T. Głowiak, CrystEngComm 3, 262 (2001) http://dx.doi.org/10.1039/b109456d[Crossref]
• [26] J. Maroszová, L. Martiška, D. Valigura, M. Koman, T. Głowiak, Acta Cryst. E62, m1164 (2006)
• [27] N.N. Hoang, F. Valach, L. Macášková, M. Melník, Acta Cryst. C48, 1933 (1993)
• [28] Š. Lörinc, M. Koman, M. J. Melník, Moncol, D. Ondrušová, Acta Cryst. E60, m590 (2004)
• [29] V. Zeleňák, I. Cisařová, M. Sabo, P. Llewellyn, K. Gyoryova, J. Coord. Chem. 57, 87 (2004) http://dx.doi.org/10.1080/00958970410001662444[Crossref]
• [30] P. Stachová, M. Korabik, M. Koman, M. Melník, J. Mrozinski, T. Głowiak, M. Mazúr, D. Valigura, Inorg. Chem. Acta 359, 1275 (2006) http://dx.doi.org/10.1016/j.ica.2005.10.040[Crossref]
• [31] M. Melník, K. Smolander, P. Sharrock, Inorg. Chim. Acta 103, 187 (1985) http://dx.doi.org/10.1016/S0020-1693(00)87488-5[Crossref]
• [32] J. Moncol, P. Segľa, J. Jašková, A. Fischer, M. Melník, Acta Cryst. E63, m698 (2007)
• [33] J. Moncol, J. Maroszová, M. Melník, M. Koman, Acta Cryst. C63, m114 (2007)
• [34] B. Viossat, F.T. Greenaway, G. Morgant, J.-C. Daran, N.-H. Dung, J.R.J. Sorenson, J. Inorg. Biochem. 99, 355 (2005) http://dx.doi.org/10.1016/j.jinorgbio.2004.10.001[Crossref]
• [35] R.W. Hooft, COLLECT (Nonius BV Delft, The Netherlands, 1998)
• [36] Z. Otwinowski, W. Minor, Meth. Enzymol. 276, 307 (1997) http://dx.doi.org/10.1016/S0076-6879(97)76066-X[Crossref]
• [37] Oxford Diffraction, CrysAlis CCD and CrysAlis RED (Oxford Diffraction Poland, Wrocław, Poland, 2003)
• [38] R.H. Blessing, Acta Cryst. A51, 33(1995)
• [39] R.C. Clark, J.S. Reid, Acta Cryst. A51, 887 (1995)
• [40] A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Cryst. 32, 115 (1999) http://dx.doi.org/10.1107/S0021889898007717[Crossref]
• [41] G.M. Sheldrick, Acta Cryst. A64, 112 (2008)
• [42] A.L. Spek, J. Appl. Cryst. 36, 7 (2003) http://dx.doi.org/10.1107/S0021889802022112[Crossref]
• [43] L.J. Farrugia, J. Appl. Cryst. 30, 565 (1997) http://dx.doi.org/10.1107/S0021889897003117[Crossref]
• [44] B.J. Hathaway, D.E. Billing, Coord. Chem. Rev. 5, 143 (1970) http://dx.doi.org/10.1016/S0010-8545(00)80135-6[Crossref]
• [45] M. Koman, M. Melník, T. Głowiak, J. Coord. Chem. 44, 133 (1998) http://dx.doi.org/10.1080/00958979808022887[Crossref]
• [46] F.T. Greenaway, E. Riviere, J.J. Girerd, X. Labouze, G. Morgant, B. Viossat, J.-C. Daran, M. Arveiller Roch, N.-H. Dung. J. Inorg. Biochem. 76, 19 (1999) http://dx.doi.org/10.1016/S0162-0134(99)00104-X[Crossref]
• [47] J. Bernstein, R.E. Davis, L. Shimoni, N.-L. Chang, Angew. Chem. Int. Ed. Engl. 34, 1555 (1995) http://dx.doi.org/10.1002/anie.199515551[Crossref]
• [48] C. Janiak, J. Chem. Soc., Dalton Trans. p. 3885 (2000)
• [49] W. Addison, T.N. Rao, J. Reedijk, J. Rija, G.C. Verchoors, J. Chem. Soc., Dalton Trans. 1349 (1984)
• [50] B.J. Hathaway, P.G. Hodgson, J. Inorg. Nucl. Chem. 35, 4071 (1973) http://dx.doi.org/10.1016/0022-1902(73)80395-1[Crossref]
• [51] M. Melník, Ľ. Macášková, C.E. Holloway, J. Coord. Chem. 30, 145 (1993) http://dx.doi.org/10.1080/00958979308024666[Crossref]
• [52] M. Melník, C.E. Holloway, J. Coord. Chem. 49, 69 (1999) http://dx.doi.org/10.1080/00958979908024375[Crossref]
• [53] C. Dendrinou-Samara, D.P. Kessisoglou, P.D. Jannakoudakis, G.E. Manoussakis, D. Mentzafos, A. Terzis, J. Chem. Soc., Dalton Trans. 3259 (1992)

Identifiers

DOI

10.2478/s11532-011-0023-9