Synthesis and characterization of coordination polymers prepared from CuII and NiII cyclam perchlorate and carmosine

• Authors: Mihaela Vlassa , George Borodi , Gabriela Blăniţa , Ileana Cojocaru , Mircea Vlassa , Cristian Silvestru
• Languages of publication: EN

Abstracts

EN

Reaction of [CuII(cyclam)](ClO4)2 or [NiII(cyclam)](ClO4)2 in DMF with aqueous 4-hydroxy-3-(4-sulfonato-1-naphthylazo)naphthalen-1-sulfonate disodium salt (carmoisine) yielded coordination polymers {[CuII(cyclam)](carmoisine dianion)(H2O)5}n and powder {[NiII(cyclam)](carmoisine dianion)}n, respectively (cyclam = 1,4,8,11-tetrazacyclotetradecane). They were characterized by powder X-ray diffraction, IR, Raman spectrometry and TGA.

Keywords

EN

Coordination polymer; Cyclam; Self-assembly; Azo dye

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2011
• Volume: 9
• Issue: 2
• Pages: 224-231

Dates

published

1 - 4 - 2011

online

17 - 2 - 2011

Contributors

author

Mihaela Vlassa

• Babes-Bolyai University

author

George Borodi

• National Institute for Research and Development of Isotopic and Molecular Technologies

author

Gabriela Blăniţa

• National Institute for Research and Development of Isotopic and Molecular Technologies

author

Ileana Cojocaru

• Craiova University

author

Mircea Vlassa

• Babes-Bolyai University

author

Cristian Silvestru

• Babes-Bolyai University

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Identifiers

DOI

10.2478/s11532-010-0141-9